Regulating Crystal Orientation in VO 2 for Aqueous Zinc Batteries with Enhanced Pseudocapacitance

Although aqueous zinc batteries have attracted extensive interest, they are limited by relatively low rate capabilities and poor cyclic stability of cathodes. The crystal orientation of the cathode is one important factor influencing electrochemical properties. However, it has rarely been investigat...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:ACS applied materials & interfaces 2024-02, Vol.16 (8), p.10009-10018
Hauptverfasser: Wang, Weijia, Feng, Cheng, Lei, Lin, Yang, Xueya, Li, Xiaomin, Ma, Longtao, Zhang, Mingchang, Fan, Huiqing
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 10018
container_issue 8
container_start_page 10009
container_title ACS applied materials & interfaces
container_volume 16
creator Wang, Weijia
Feng, Cheng
Lei, Lin
Yang, Xueya
Li, Xiaomin
Ma, Longtao
Zhang, Mingchang
Fan, Huiqing
description Although aqueous zinc batteries have attracted extensive interest, they are limited by relatively low rate capabilities and poor cyclic stability of cathodes. The crystal orientation of the cathode is one important factor influencing electrochemical properties. However, it has rarely been investigated. Herein, VO cathodes with different crystal orientations are developed via tuning the number of hydroxyl groups in polyol, such as using glycerol, erythritol, xylitol, or mannitol. The polyols serve as a reductant as well as a structure-directing agent through a hydrothermal reaction. Xylitol-derived VO shows a (110)-orientated crystalline structure and ultrathin nanosheet morphology. Such features greatly enhance the pseudocapacitance to 76.1% at a scan rate of 1.0 mV s , which is significantly larger than that (61.6%) of the (001)-oriented VO derived from glycerol. The corresponding aqueous zinc batteries exhibit a high energy storage performance with a reversible specific capacity of 317 mAh g at 0.5 A g , rate ability of 220 mAh g at 10 A g , and capacity retention of 81.0% at 10 A g over 2000 cycles. This work demonstrates a facile method for tailoring VO crystal orientations, offers an understanding of the Zn storage mechanism upon different VO facets, and provides a novel method to develop cathode materials toward advanced aqueous zinc batteries.
doi_str_mv 10.1021/acsami.3c15209
format Article
fullrecord <record><control><sourceid>pubmed_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1021_acsami_3c15209</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>38376956</sourcerecordid><originalsourceid>FETCH-LOGICAL-c1076-fd6e55c75c333ab0032b188aabaa3cb42b64720f655d60ab678779c41d009ee03</originalsourceid><addsrcrecordid>eNo9kE1PwkAYhDdGI4hePZr9A8V3v9sjEvxISGqMevDSvN1uYQ1ssdvG8O-FgJxmMpmZw0PILYMxA87u0UZc-7GwTHHIzsiQZVImKVf8_OSlHJCrGL8BtOCgLslApMLoTOkhwTe36FfY-bCg03YbO1zRvPUudLusCdQH-plTTuumpZOf3jV9pF8-WPqAXed2xUh_fbeks7DEYF1FX6Prq8biBq3v9tE1uahxFd3NUUfk43H2Pn1O5vnTy3QyTywDo5O60k4pa5QVQmAJIHjJ0hSxRBS2lLzU0nCotVKVBiy1SY3JrGQVQOYciBEZH35t28TYurrYtH6N7bZgUOxZFQdWxZHVbnB3GGz6cu2qU_0fjvgDafdm1Q</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Regulating Crystal Orientation in VO 2 for Aqueous Zinc Batteries with Enhanced Pseudocapacitance</title><source>American Chemical Society (ACS) Journals</source><creator>Wang, Weijia ; Feng, Cheng ; Lei, Lin ; Yang, Xueya ; Li, Xiaomin ; Ma, Longtao ; Zhang, Mingchang ; Fan, Huiqing</creator><creatorcontrib>Wang, Weijia ; Feng, Cheng ; Lei, Lin ; Yang, Xueya ; Li, Xiaomin ; Ma, Longtao ; Zhang, Mingchang ; Fan, Huiqing</creatorcontrib><description>Although aqueous zinc batteries have attracted extensive interest, they are limited by relatively low rate capabilities and poor cyclic stability of cathodes. The crystal orientation of the cathode is one important factor influencing electrochemical properties. However, it has rarely been investigated. Herein, VO cathodes with different crystal orientations are developed via tuning the number of hydroxyl groups in polyol, such as using glycerol, erythritol, xylitol, or mannitol. The polyols serve as a reductant as well as a structure-directing agent through a hydrothermal reaction. Xylitol-derived VO shows a (110)-orientated crystalline structure and ultrathin nanosheet morphology. Such features greatly enhance the pseudocapacitance to 76.1% at a scan rate of 1.0 mV s , which is significantly larger than that (61.6%) of the (001)-oriented VO derived from glycerol. The corresponding aqueous zinc batteries exhibit a high energy storage performance with a reversible specific capacity of 317 mAh g at 0.5 A g , rate ability of 220 mAh g at 10 A g , and capacity retention of 81.0% at 10 A g over 2000 cycles. This work demonstrates a facile method for tailoring VO crystal orientations, offers an understanding of the Zn storage mechanism upon different VO facets, and provides a novel method to develop cathode materials toward advanced aqueous zinc batteries.</description><identifier>ISSN: 1944-8244</identifier><identifier>EISSN: 1944-8252</identifier><identifier>DOI: 10.1021/acsami.3c15209</identifier><identifier>PMID: 38376956</identifier><language>eng</language><publisher>United States</publisher><ispartof>ACS applied materials &amp; interfaces, 2024-02, Vol.16 (8), p.10009-10018</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1076-fd6e55c75c333ab0032b188aabaa3cb42b64720f655d60ab678779c41d009ee03</citedby><cites>FETCH-LOGICAL-c1076-fd6e55c75c333ab0032b188aabaa3cb42b64720f655d60ab678779c41d009ee03</cites><orcidid>0000-0002-4899-7378 ; 0000-0003-0164-9322 ; 0000-0002-5338-7136</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,2765,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/38376956$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Wang, Weijia</creatorcontrib><creatorcontrib>Feng, Cheng</creatorcontrib><creatorcontrib>Lei, Lin</creatorcontrib><creatorcontrib>Yang, Xueya</creatorcontrib><creatorcontrib>Li, Xiaomin</creatorcontrib><creatorcontrib>Ma, Longtao</creatorcontrib><creatorcontrib>Zhang, Mingchang</creatorcontrib><creatorcontrib>Fan, Huiqing</creatorcontrib><title>Regulating Crystal Orientation in VO 2 for Aqueous Zinc Batteries with Enhanced Pseudocapacitance</title><title>ACS applied materials &amp; interfaces</title><addtitle>ACS Appl Mater Interfaces</addtitle><description>Although aqueous zinc batteries have attracted extensive interest, they are limited by relatively low rate capabilities and poor cyclic stability of cathodes. The crystal orientation of the cathode is one important factor influencing electrochemical properties. However, it has rarely been investigated. Herein, VO cathodes with different crystal orientations are developed via tuning the number of hydroxyl groups in polyol, such as using glycerol, erythritol, xylitol, or mannitol. The polyols serve as a reductant as well as a structure-directing agent through a hydrothermal reaction. Xylitol-derived VO shows a (110)-orientated crystalline structure and ultrathin nanosheet morphology. Such features greatly enhance the pseudocapacitance to 76.1% at a scan rate of 1.0 mV s , which is significantly larger than that (61.6%) of the (001)-oriented VO derived from glycerol. The corresponding aqueous zinc batteries exhibit a high energy storage performance with a reversible specific capacity of 317 mAh g at 0.5 A g , rate ability of 220 mAh g at 10 A g , and capacity retention of 81.0% at 10 A g over 2000 cycles. This work demonstrates a facile method for tailoring VO crystal orientations, offers an understanding of the Zn storage mechanism upon different VO facets, and provides a novel method to develop cathode materials toward advanced aqueous zinc batteries.</description><issn>1944-8244</issn><issn>1944-8252</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNo9kE1PwkAYhDdGI4hePZr9A8V3v9sjEvxISGqMevDSvN1uYQ1ssdvG8O-FgJxmMpmZw0PILYMxA87u0UZc-7GwTHHIzsiQZVImKVf8_OSlHJCrGL8BtOCgLslApMLoTOkhwTe36FfY-bCg03YbO1zRvPUudLusCdQH-plTTuumpZOf3jV9pF8-WPqAXed2xUh_fbeks7DEYF1FX6Prq8biBq3v9tE1uahxFd3NUUfk43H2Pn1O5vnTy3QyTywDo5O60k4pa5QVQmAJIHjJ0hSxRBS2lLzU0nCotVKVBiy1SY3JrGQVQOYciBEZH35t28TYurrYtH6N7bZgUOxZFQdWxZHVbnB3GGz6cu2qU_0fjvgDafdm1Q</recordid><startdate>20240228</startdate><enddate>20240228</enddate><creator>Wang, Weijia</creator><creator>Feng, Cheng</creator><creator>Lei, Lin</creator><creator>Yang, Xueya</creator><creator>Li, Xiaomin</creator><creator>Ma, Longtao</creator><creator>Zhang, Mingchang</creator><creator>Fan, Huiqing</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-4899-7378</orcidid><orcidid>https://orcid.org/0000-0003-0164-9322</orcidid><orcidid>https://orcid.org/0000-0002-5338-7136</orcidid></search><sort><creationdate>20240228</creationdate><title>Regulating Crystal Orientation in VO 2 for Aqueous Zinc Batteries with Enhanced Pseudocapacitance</title><author>Wang, Weijia ; Feng, Cheng ; Lei, Lin ; Yang, Xueya ; Li, Xiaomin ; Ma, Longtao ; Zhang, Mingchang ; Fan, Huiqing</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1076-fd6e55c75c333ab0032b188aabaa3cb42b64720f655d60ab678779c41d009ee03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Weijia</creatorcontrib><creatorcontrib>Feng, Cheng</creatorcontrib><creatorcontrib>Lei, Lin</creatorcontrib><creatorcontrib>Yang, Xueya</creatorcontrib><creatorcontrib>Li, Xiaomin</creatorcontrib><creatorcontrib>Ma, Longtao</creatorcontrib><creatorcontrib>Zhang, Mingchang</creatorcontrib><creatorcontrib>Fan, Huiqing</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><jtitle>ACS applied materials &amp; interfaces</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Weijia</au><au>Feng, Cheng</au><au>Lei, Lin</au><au>Yang, Xueya</au><au>Li, Xiaomin</au><au>Ma, Longtao</au><au>Zhang, Mingchang</au><au>Fan, Huiqing</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Regulating Crystal Orientation in VO 2 for Aqueous Zinc Batteries with Enhanced Pseudocapacitance</atitle><jtitle>ACS applied materials &amp; interfaces</jtitle><addtitle>ACS Appl Mater Interfaces</addtitle><date>2024-02-28</date><risdate>2024</risdate><volume>16</volume><issue>8</issue><spage>10009</spage><epage>10018</epage><pages>10009-10018</pages><issn>1944-8244</issn><eissn>1944-8252</eissn><abstract>Although aqueous zinc batteries have attracted extensive interest, they are limited by relatively low rate capabilities and poor cyclic stability of cathodes. The crystal orientation of the cathode is one important factor influencing electrochemical properties. However, it has rarely been investigated. Herein, VO cathodes with different crystal orientations are developed via tuning the number of hydroxyl groups in polyol, such as using glycerol, erythritol, xylitol, or mannitol. The polyols serve as a reductant as well as a structure-directing agent through a hydrothermal reaction. Xylitol-derived VO shows a (110)-orientated crystalline structure and ultrathin nanosheet morphology. Such features greatly enhance the pseudocapacitance to 76.1% at a scan rate of 1.0 mV s , which is significantly larger than that (61.6%) of the (001)-oriented VO derived from glycerol. The corresponding aqueous zinc batteries exhibit a high energy storage performance with a reversible specific capacity of 317 mAh g at 0.5 A g , rate ability of 220 mAh g at 10 A g , and capacity retention of 81.0% at 10 A g over 2000 cycles. This work demonstrates a facile method for tailoring VO crystal orientations, offers an understanding of the Zn storage mechanism upon different VO facets, and provides a novel method to develop cathode materials toward advanced aqueous zinc batteries.</abstract><cop>United States</cop><pmid>38376956</pmid><doi>10.1021/acsami.3c15209</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0002-4899-7378</orcidid><orcidid>https://orcid.org/0000-0003-0164-9322</orcidid><orcidid>https://orcid.org/0000-0002-5338-7136</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 1944-8244
ispartof ACS applied materials & interfaces, 2024-02, Vol.16 (8), p.10009-10018
issn 1944-8244
1944-8252
language eng
recordid cdi_crossref_primary_10_1021_acsami_3c15209
source American Chemical Society (ACS) Journals
title Regulating Crystal Orientation in VO 2 for Aqueous Zinc Batteries with Enhanced Pseudocapacitance
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-24T22%3A41%3A08IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-pubmed_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Regulating%20Crystal%20Orientation%20in%20VO%202%20for%20Aqueous%20Zinc%20Batteries%20with%20Enhanced%20Pseudocapacitance&rft.jtitle=ACS%20applied%20materials%20&%20interfaces&rft.au=Wang,%20Weijia&rft.date=2024-02-28&rft.volume=16&rft.issue=8&rft.spage=10009&rft.epage=10018&rft.pages=10009-10018&rft.issn=1944-8244&rft.eissn=1944-8252&rft_id=info:doi/10.1021/acsami.3c15209&rft_dat=%3Cpubmed_cross%3E38376956%3C/pubmed_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/38376956&rfr_iscdi=true