Fully Degradable Thioester-Functional Homo- and Alternating Copolymers Prepared through Thiocarbonyl Addition–Ring-Opening RAFT Radical Polymerization

The radical ring-opening polymerization (RROP) of thionolactones provides access to thioester backbone-functional copolymers but has, to date, only been demonstrated on acrylic copolymers. Herein, the thionolactone dibenzo­[c,e]­oxepane-5-thione (DOT) was subjected to azobisisobutyronitrile (AIBN)-i...

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Veröffentlicht in:	Macromolecules 2020-01, Vol.53 (2), p.539-547
Hauptverfasser:	Spick, Matt P, Bingham, Nathaniel M, Li, Yuman, de Jesus, Janella, Costa, Catia, Bailey, Melanie J, Roth, Peter J
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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