Fundamental Kinetics of Living Anionic Polymerization of Isocyanates Emerging by the Sodium Diphenylmethane-Mediated Initiation

Anionic polymerization of n-hexyl isocyanate (HIC) in THF at −98 °C under 10–6 Torr for the kinetic study was performed by the initiation of sodium diphenylmethane (NaDPM) in either the absence or presence of sodium tetraphenylborate (NaBPh4; [NaBPh4]0/[NaDPM]0 = 0 or 5). The common-ion effect of Na...

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Veröffentlicht in:	Macromolecules 2018-09, Vol.51 (17), p.6771-6781
Hauptverfasser:	Chae, Chang-Geun, Bak, In-Gyu, Lee, Jae-Suk
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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