Rationally Controlling the Self-Assembly Behavior of Triarmed POSS–Organic Hybrid Macromolecules: From Giant Surfactants to Macroions

Two triarmed organic–inorganic hybrid materials based on carboxylic acid-functionalized polyhedral oligomeric silsesquioxane (APOSS) with/without PS linkers are designed and synthesized (tri-PS-APOSS and tri-APOSS). They can both self-assemble into hollow spherical nanostructures in water/organic mi...

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Veröffentlicht in:Macromolecules 2017-07, Vol.50 (13), p.5042-5050
Hauptverfasser: Zhang, Wei, Chu, Yang, Mu, Gaoyan, Eghtesadi, Seyed Ali, Liu, Yuchu, Zhou, Zhe, Lu, Xinlin, Kashfipour, Marjan Alsadat, Lillard, Robert Scott, Yue, Kan, Liu, Tianbo, Cheng, Stephen Z. D
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container_end_page 5050
container_issue 13
container_start_page 5042
container_title Macromolecules
container_volume 50
creator Zhang, Wei
Chu, Yang
Mu, Gaoyan
Eghtesadi, Seyed Ali
Liu, Yuchu
Zhou, Zhe
Lu, Xinlin
Kashfipour, Marjan Alsadat
Lillard, Robert Scott
Yue, Kan
Liu, Tianbo
Cheng, Stephen Z. D
description Two triarmed organic–inorganic hybrid materials based on carboxylic acid-functionalized polyhedral oligomeric silsesquioxane (APOSS) with/without PS linkers are designed and synthesized (tri-PS-APOSS and tri-APOSS). They can both self-assemble into hollow spherical nanostructures in water/organic mixed solvents, as confirmed by light scattering and TEM techniques, yet they possess completely different mechanisms and driving forces. With the PS linkers, the hybrid forms bilayer vesicles similar to surfactants; while without the PS linkers, the hybrid behaves like hydrophilic macroions and assembles into single-layered, vesicle-like “blackberry”-type structure. Consequently, the trend of the assembly size in response to the change of the solvent polarity is different for the two scenarios. This work shows a simple, universal approach of controlling the mechanism and product of the self-assembly process via minor adjustment of the organic–inorganic hybrid structures.
doi_str_mv 10.1021/acs.macromol.7b00963
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title Rationally Controlling the Self-Assembly Behavior of Triarmed POSS–Organic Hybrid Macromolecules: From Giant Surfactants to Macroions
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