Rationally Controlling the Self-Assembly Behavior of Triarmed POSS–Organic Hybrid Macromolecules: From Giant Surfactants to Macroions
Two triarmed organic–inorganic hybrid materials based on carboxylic acid-functionalized polyhedral oligomeric silsesquioxane (APOSS) with/without PS linkers are designed and synthesized (tri-PS-APOSS and tri-APOSS). They can both self-assemble into hollow spherical nanostructures in water/organic mi...
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Veröffentlicht in: | Macromolecules 2017-07, Vol.50 (13), p.5042-5050 |
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creator | Zhang, Wei Chu, Yang Mu, Gaoyan Eghtesadi, Seyed Ali Liu, Yuchu Zhou, Zhe Lu, Xinlin Kashfipour, Marjan Alsadat Lillard, Robert Scott Yue, Kan Liu, Tianbo Cheng, Stephen Z. D |
description | Two triarmed organic–inorganic hybrid materials based on carboxylic acid-functionalized polyhedral oligomeric silsesquioxane (APOSS) with/without PS linkers are designed and synthesized (tri-PS-APOSS and tri-APOSS). They can both self-assemble into hollow spherical nanostructures in water/organic mixed solvents, as confirmed by light scattering and TEM techniques, yet they possess completely different mechanisms and driving forces. With the PS linkers, the hybrid forms bilayer vesicles similar to surfactants; while without the PS linkers, the hybrid behaves like hydrophilic macroions and assembles into single-layered, vesicle-like “blackberry”-type structure. Consequently, the trend of the assembly size in response to the change of the solvent polarity is different for the two scenarios. This work shows a simple, universal approach of controlling the mechanism and product of the self-assembly process via minor adjustment of the organic–inorganic hybrid structures. |
doi_str_mv | 10.1021/acs.macromol.7b00963 |
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Consequently, the trend of the assembly size in response to the change of the solvent polarity is different for the two scenarios. 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Consequently, the trend of the assembly size in response to the change of the solvent polarity is different for the two scenarios. 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With the PS linkers, the hybrid forms bilayer vesicles similar to surfactants; while without the PS linkers, the hybrid behaves like hydrophilic macroions and assembles into single-layered, vesicle-like “blackberry”-type structure. Consequently, the trend of the assembly size in response to the change of the solvent polarity is different for the two scenarios. This work shows a simple, universal approach of controlling the mechanism and product of the self-assembly process via minor adjustment of the organic–inorganic hybrid structures.</abstract><pub>American Chemical Society</pub><doi>10.1021/acs.macromol.7b00963</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0001-9780-8724</orcidid><orcidid>https://orcid.org/0000-0002-8181-1790</orcidid><orcidid>https://orcid.org/0000-0003-1448-0546</orcidid><orcidid>https://orcid.org/0000-0002-9321-6411</orcidid></addata></record> |
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title | Rationally Controlling the Self-Assembly Behavior of Triarmed POSS–Organic Hybrid Macromolecules: From Giant Surfactants to Macroions |
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