A Molecular Thermodynamic Model of Complexation in Mixtures of Oppositely Charged Polyelectrolytes with Explicit Account of Charge Association/Dissociation

Into an extended Voorn–Overbeek (EVO) free energy model of polyelectrolyte (PE) complexation and phase behavior, we incorporate three classes of short-ranged electrostatic effects, namely counterion association–dissociation, cross-chain ion pairing (IP), and charge regulation by treating each as a r...

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Veröffentlicht in:	Macromolecules 2016-12, Vol.49 (24), p.9706-9719
Hauptverfasser:	Salehi, Ali, Larson, Ronald G
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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