Catalytic Synthesis of Secondary Amine-Containing Polymers: Variable Hydrogen Bonding for Tunable Rheological Properties

Catalytic Synthesis of Secondary Amine-Containing Polymers: Variable Hydrogen Bonding for Tunable Rheological Properties

A synthetic protocol using atom-economic, catalytic hydroaminoalkylation and ring-opening metathesis polymerization (ROMP) has been developed for the versatile synthesis of a new class of aryl-substituted secondary amine-containing polymers. This catalytic route minimizes waste generation and avoids...

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Veröffentlicht in:Macromolecules 2016-06, Vol.49 (12), p.4423-4430
Hauptverfasser: Perry, Mitchell R, Ebrahimi, Tannaz, Morgan, Erin, Edwards, Peter M, Hatzikiriakos, Savvas G, Schafer, Laurel L
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container_end_page 4430
container_issue 12
container_start_page 4423
container_title Macromolecules
container_volume 49
creator Perry, Mitchell R
Ebrahimi, Tannaz
Morgan, Erin
Edwards, Peter M
Hatzikiriakos, Savvas G
Schafer, Laurel L
description A synthetic protocol using atom-economic, catalytic hydroaminoalkylation and ring-opening metathesis polymerization (ROMP) has been developed for the versatile synthesis of a new class of aryl-substituted secondary amine-containing polymers. This catalytic route minimizes waste generation and avoids protection/deprotection protocols, postpolymerization modification, and byproduct formation. Different amines can be readily incorporated to access variable hydrogen-bonding characteristics. Thermal and melt rheological characterization has shown the profound effect of hydrogen bonding on the bulk properties of these amine-containing norbornene polymers.
doi_str_mv 10.1021/acs.macromol.6b00306
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title Catalytic Synthesis of Secondary Amine-Containing Polymers: Variable Hydrogen Bonding for Tunable Rheological Properties
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