Termination Mechanism in the Radical Polymerization of Methyl Methacrylate and Styrene Determined by the Reaction of Structurally Well-Defined Polymer End Radicals

A novel method to determine the termination mechanism of radical polymerization, i.e., the selectivity between disproportionation (Disp) and combination (Comb), is developed. The method relies on product analyses of the reaction of polymer-end radicals, which are generated from structurally well-con...

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Veröffentlicht in:Macromolecules 2015-09, Vol.48 (18), p.6450-6456
Hauptverfasser: Nakamura, Yasuyuki, Yamago, Shigeru
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
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