Prop-2-yn-1-yl 2‑Bromo-2-methylpropanoate: Identification and Suppression of Side Reactions of a Commonly Used Terminal Alkyne-Functional ATRP Initiator

The atom transfer radical polymerization (ATRP) of styrene was investigated using the popular alkyne-functional initiator prop-2-yn-1-yl 2-bromo-2-methylpropanoate (PBiB). The polymerization kinetics and evolution of molecular weight as a function of monomer conversion were systematically studied wi...

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Veröffentlicht in:	Macromolecules 2015-06, Vol.48 (12), p.3803-3810
Hauptverfasser:	Storms-Miller, William K, Pugh, Coleen
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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