In Situ Monitoring of Polymerization-Induced Self-Assembly and Gelation During the Synthesis of Triblock Copolymers via Time-Resolved Small-Angle X‑ray Scattering and Rheology

The polymerization of solvophobic monomers from both ends of solvophilic polymers produces BAB triblock copolymers in solution. The self-assembly of the extending solvophobic blocks may lead to network formation and gelation. This process, referred to as polymerization-induced self-assembly (PISA) i...

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Veröffentlicht in:Macromolecules 2023-06, Vol.56 (11), p.4354-4361
Hauptverfasser: Yamanaka, Riku, Sugawara-Narutaki, Ayae, Takahashi, Rintaro
Format: Artikel
Sprache:eng
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