Ethylene/Myrcene Copolymers as New Bio-Based Elastomers Prepared by Coordination Polymerization Using Titanium Catalysts

The synthesis of ethylene/myrcene copolymers was performed using half-titanocene catalysts in the presence of a methylaluminoxane (MAO) cocatalyst. Cyclopentadienyl-phenoxide catalysts, Cp*TiCl2(O-2,6- i Pr2-4-RC6H2) [R = H (1), SiEt3 (2)], showed rather efficient myrcene (My) incorporation to affor...

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Veröffentlicht in:Macromolecules 2021-11, Vol.54 (21), p.10049-10058
Hauptverfasser: Kitphaitun, Suphitchaya, Chaimongkolkunasin, Sapanna, Manit, Jeeranun, Makino, Ryoji, Kadota, Joji, Hirano, Hiroshi, Nomura, Kotohiro
Format: Artikel
Sprache:eng
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