Highly Regioselective and Helix-Sense Selective Living Polymerization of Phenyl and Alkoxyallene Using Chiral Nickel(II) Catalysts

Facile synthesis of high optically active helical polymers from achiral monomers still remains a great challenge. In this work, two chiral Ni­(II) catalysts bearing chiral R- or S-2a ligands were facilely prepared which can efficiently initiate the living/controlled polymerization of allene monomers...

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Veröffentlicht in:	Macromolecules 2021-01, Vol.54 (2), p.679-686
Hauptverfasser:	Zhou, Li, Li, Chong-Long, Gao, Run-Tan, Kang, Shu-Ming, Xu, Lei, Xu, Xun-Hui, Liu, Na, Wu, Zong-Quan
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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