Cationic Copolymerization of Styrene Derivatives and Oxiranes via Concurrent Vinyl-Addition and Ring-Opening Mechanisms: Multiblock Copolymer Formation via Occasional Crossover Reactions

Styrene derivatives were demonstrated to cationically copolymerize with 2,2-disubstituted oxiranes, which can generate a tertiary carbocation by the ring opening of the oxonium ion, through crossover reactions. The copolymerization proceeded with comparable consumptions of both the vinyl and cyclic...

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Veröffentlicht in:	Macromolecules 2020-07, Vol.53 (13), p.5255-5265
Hauptverfasser:	Kanazawa, Arihiro, Aoshima, Sadahito
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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