Interface Catalysts of Ni 3 Fe 1 Layered Double Hydroxide and Titanium Carbide for High-Performance Water Oxidation in Alkaline and Natural Conditions
The electrocatalytic oxygen evolution reaction (OER) is important for many renewable energy technologies. Developing cost-effective electrocatalysts with high performance remains a great challenge. Here, we successfully demonstrate our novel interface catalyst comprised of Ni Fe -based layered doubl...
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| Veröffentlicht in: | The journal of physical chemistry letters 2023-06, Vol.14 (24), p.5692-5700 |
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| creator | Song, Fuzhan Debow, Shaun Zhang, Tong Qian, Yuqin Huang-Fu, Zhi-Chao Munns, Kaylee Schmidt, Sydney Fisher, Haley Brown, Jesse B Su, Yanqing Zander, Zachary DeLacy, Brendan G Mirotznik, Mark S Opila, Robert L Rao, Yi |
| description | The electrocatalytic oxygen evolution reaction (OER) is important for many renewable energy technologies. Developing cost-effective electrocatalysts with high performance remains a great challenge. Here, we successfully demonstrate our novel interface catalyst comprised of Ni
Fe
-based layered double hydroxides (Ni
Fe
-LDH) vertically immobilized on a two-dimensional MXene (Ti
C
T
) surface. The Ni
Fe
-LDH/Ti
C
T
yielded an anodic OER current of 100 mA cm
at 0.28 V versus reversible hydrogen electrode (RHE), nearly 74 times lower than that of the pristine Ni
Fe
-LDH. Furthermore, the Ni
Fe
-LDH/Ti
C
T
catalyst requires an overpotential of only 0.31 V versus RHE to deliver an industrial-level current density as high as 1000 mA cm
. Such excellent OER activity was attributed to the synergistic interface effect between Ni
Fe
-LDH and Ti
C
T
. Density functional theory (DFT) results further reveal that the Ti
C
T
support can efficiently accelerate the electron extraction from Ni
Fe
-LDH and tailor the electronic structure of catalytic sites, resulting in enhanced OER performance. |
| doi_str_mv | 10.1021/acs.jpclett.3c00655 |
| format | Article |
| fullrecord | <record><control><sourceid>pubmed_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1021_acs_jpclett_3c00655</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>37315210</sourcerecordid><originalsourceid>FETCH-LOGICAL-c1170-785f06f3e5ac216eb4eaac6d70877be65a8d364fa1de610ce9c01570a5dc5e0e3</originalsourceid><addsrcrecordid>eNpNkN1KAzEQRoMoVqtPIEheYGvSNLvby7JaWyitFxUvl9lkVlP3pyRZcF_E5zWlVbyaYZjzDXMIueNsxNmYP4Byo91eVej9SCjGYinPyBWfTtIo4ak8_9cPyLVzu7AyZWlySQYiEVyOObsi38vGoy1BIc3AQ9U772hb0rWhgs6RcrqCHi1q-th2RYV00WvbfhmNFBpNt8ZDY7o6wLY4DMvW0oV5_4heQmpra2hC8huEG3QTKPCmbahp6Kz6hMo0x5Q1-M5CRbO20eaw4W7IRQmVw9tTHZLX-dM2W0SrzfMym60ixXnCoiSVJYtLgRLUmMdYTBBAxToJbyYFxhJSLeJJCVxjzJnCqWJcJgykVhIZiiERx1xlW-cslvnemhpsn3OWHyznwXJ-spyfLAfq_kjtu6JG_cf8ahU_eJ19yA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Interface Catalysts of Ni 3 Fe 1 Layered Double Hydroxide and Titanium Carbide for High-Performance Water Oxidation in Alkaline and Natural Conditions</title><source>ACS Publications</source><creator>Song, Fuzhan ; Debow, Shaun ; Zhang, Tong ; Qian, Yuqin ; Huang-Fu, Zhi-Chao ; Munns, Kaylee ; Schmidt, Sydney ; Fisher, Haley ; Brown, Jesse B ; Su, Yanqing ; Zander, Zachary ; DeLacy, Brendan G ; Mirotznik, Mark S ; Opila, Robert L ; Rao, Yi</creator><creatorcontrib>Song, Fuzhan ; Debow, Shaun ; Zhang, Tong ; Qian, Yuqin ; Huang-Fu, Zhi-Chao ; Munns, Kaylee ; Schmidt, Sydney ; Fisher, Haley ; Brown, Jesse B ; Su, Yanqing ; Zander, Zachary ; DeLacy, Brendan G ; Mirotznik, Mark S ; Opila, Robert L ; Rao, Yi</creatorcontrib><description>The electrocatalytic oxygen evolution reaction (OER) is important for many renewable energy technologies. Developing cost-effective electrocatalysts with high performance remains a great challenge. Here, we successfully demonstrate our novel interface catalyst comprised of Ni
Fe
-based layered double hydroxides (Ni
Fe
-LDH) vertically immobilized on a two-dimensional MXene (Ti
C
T
) surface. The Ni
Fe
-LDH/Ti
C
T
yielded an anodic OER current of 100 mA cm
at 0.28 V versus reversible hydrogen electrode (RHE), nearly 74 times lower than that of the pristine Ni
Fe
-LDH. Furthermore, the Ni
Fe
-LDH/Ti
C
T
catalyst requires an overpotential of only 0.31 V versus RHE to deliver an industrial-level current density as high as 1000 mA cm
. Such excellent OER activity was attributed to the synergistic interface effect between Ni
Fe
-LDH and Ti
C
T
. Density functional theory (DFT) results further reveal that the Ti
C
T
support can efficiently accelerate the electron extraction from Ni
Fe
-LDH and tailor the electronic structure of catalytic sites, resulting in enhanced OER performance.</description><identifier>ISSN: 1948-7185</identifier><identifier>EISSN: 1948-7185</identifier><identifier>DOI: 10.1021/acs.jpclett.3c00655</identifier><identifier>PMID: 37315210</identifier><language>eng</language><publisher>United States</publisher><ispartof>The journal of physical chemistry letters, 2023-06, Vol.14 (24), p.5692-5700</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1170-785f06f3e5ac216eb4eaac6d70877be65a8d364fa1de610ce9c01570a5dc5e0e3</citedby><cites>FETCH-LOGICAL-c1170-785f06f3e5ac216eb4eaac6d70877be65a8d364fa1de610ce9c01570a5dc5e0e3</cites><orcidid>0000-0002-7801-4678 ; 0000-0003-0790-5905 ; 0000-0001-9882-1314</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,781,785,2766,27929,27930</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/37315210$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Song, Fuzhan</creatorcontrib><creatorcontrib>Debow, Shaun</creatorcontrib><creatorcontrib>Zhang, Tong</creatorcontrib><creatorcontrib>Qian, Yuqin</creatorcontrib><creatorcontrib>Huang-Fu, Zhi-Chao</creatorcontrib><creatorcontrib>Munns, Kaylee</creatorcontrib><creatorcontrib>Schmidt, Sydney</creatorcontrib><creatorcontrib>Fisher, Haley</creatorcontrib><creatorcontrib>Brown, Jesse B</creatorcontrib><creatorcontrib>Su, Yanqing</creatorcontrib><creatorcontrib>Zander, Zachary</creatorcontrib><creatorcontrib>DeLacy, Brendan G</creatorcontrib><creatorcontrib>Mirotznik, Mark S</creatorcontrib><creatorcontrib>Opila, Robert L</creatorcontrib><creatorcontrib>Rao, Yi</creatorcontrib><title>Interface Catalysts of Ni 3 Fe 1 Layered Double Hydroxide and Titanium Carbide for High-Performance Water Oxidation in Alkaline and Natural Conditions</title><title>The journal of physical chemistry letters</title><addtitle>J Phys Chem Lett</addtitle><description>The electrocatalytic oxygen evolution reaction (OER) is important for many renewable energy technologies. Developing cost-effective electrocatalysts with high performance remains a great challenge. Here, we successfully demonstrate our novel interface catalyst comprised of Ni
Fe
-based layered double hydroxides (Ni
Fe
-LDH) vertically immobilized on a two-dimensional MXene (Ti
C
T
) surface. The Ni
Fe
-LDH/Ti
C
T
yielded an anodic OER current of 100 mA cm
at 0.28 V versus reversible hydrogen electrode (RHE), nearly 74 times lower than that of the pristine Ni
Fe
-LDH. Furthermore, the Ni
Fe
-LDH/Ti
C
T
catalyst requires an overpotential of only 0.31 V versus RHE to deliver an industrial-level current density as high as 1000 mA cm
. Such excellent OER activity was attributed to the synergistic interface effect between Ni
Fe
-LDH and Ti
C
T
. Density functional theory (DFT) results further reveal that the Ti
C
T
support can efficiently accelerate the electron extraction from Ni
Fe
-LDH and tailor the electronic structure of catalytic sites, resulting in enhanced OER performance.</description><issn>1948-7185</issn><issn>1948-7185</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpNkN1KAzEQRoMoVqtPIEheYGvSNLvby7JaWyitFxUvl9lkVlP3pyRZcF_E5zWlVbyaYZjzDXMIueNsxNmYP4Byo91eVej9SCjGYinPyBWfTtIo4ak8_9cPyLVzu7AyZWlySQYiEVyOObsi38vGoy1BIc3AQ9U772hb0rWhgs6RcrqCHi1q-th2RYV00WvbfhmNFBpNt8ZDY7o6wLY4DMvW0oV5_4heQmpra2hC8huEG3QTKPCmbahp6Kz6hMo0x5Q1-M5CRbO20eaw4W7IRQmVw9tTHZLX-dM2W0SrzfMym60ixXnCoiSVJYtLgRLUmMdYTBBAxToJbyYFxhJSLeJJCVxjzJnCqWJcJgykVhIZiiERx1xlW-cslvnemhpsn3OWHyznwXJ-spyfLAfq_kjtu6JG_cf8ahU_eJ19yA</recordid><startdate>20230622</startdate><enddate>20230622</enddate><creator>Song, Fuzhan</creator><creator>Debow, Shaun</creator><creator>Zhang, Tong</creator><creator>Qian, Yuqin</creator><creator>Huang-Fu, Zhi-Chao</creator><creator>Munns, Kaylee</creator><creator>Schmidt, Sydney</creator><creator>Fisher, Haley</creator><creator>Brown, Jesse B</creator><creator>Su, Yanqing</creator><creator>Zander, Zachary</creator><creator>DeLacy, Brendan G</creator><creator>Mirotznik, Mark S</creator><creator>Opila, Robert L</creator><creator>Rao, Yi</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-7801-4678</orcidid><orcidid>https://orcid.org/0000-0003-0790-5905</orcidid><orcidid>https://orcid.org/0000-0001-9882-1314</orcidid></search><sort><creationdate>20230622</creationdate><title>Interface Catalysts of Ni 3 Fe 1 Layered Double Hydroxide and Titanium Carbide for High-Performance Water Oxidation in Alkaline and Natural Conditions</title><author>Song, Fuzhan ; Debow, Shaun ; Zhang, Tong ; Qian, Yuqin ; Huang-Fu, Zhi-Chao ; Munns, Kaylee ; Schmidt, Sydney ; Fisher, Haley ; Brown, Jesse B ; Su, Yanqing ; Zander, Zachary ; DeLacy, Brendan G ; Mirotznik, Mark S ; Opila, Robert L ; Rao, Yi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1170-785f06f3e5ac216eb4eaac6d70877be65a8d364fa1de610ce9c01570a5dc5e0e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Song, Fuzhan</creatorcontrib><creatorcontrib>Debow, Shaun</creatorcontrib><creatorcontrib>Zhang, Tong</creatorcontrib><creatorcontrib>Qian, Yuqin</creatorcontrib><creatorcontrib>Huang-Fu, Zhi-Chao</creatorcontrib><creatorcontrib>Munns, Kaylee</creatorcontrib><creatorcontrib>Schmidt, Sydney</creatorcontrib><creatorcontrib>Fisher, Haley</creatorcontrib><creatorcontrib>Brown, Jesse B</creatorcontrib><creatorcontrib>Su, Yanqing</creatorcontrib><creatorcontrib>Zander, Zachary</creatorcontrib><creatorcontrib>DeLacy, Brendan G</creatorcontrib><creatorcontrib>Mirotznik, Mark S</creatorcontrib><creatorcontrib>Opila, Robert L</creatorcontrib><creatorcontrib>Rao, Yi</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><jtitle>The journal of physical chemistry letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Song, Fuzhan</au><au>Debow, Shaun</au><au>Zhang, Tong</au><au>Qian, Yuqin</au><au>Huang-Fu, Zhi-Chao</au><au>Munns, Kaylee</au><au>Schmidt, Sydney</au><au>Fisher, Haley</au><au>Brown, Jesse B</au><au>Su, Yanqing</au><au>Zander, Zachary</au><au>DeLacy, Brendan G</au><au>Mirotznik, Mark S</au><au>Opila, Robert L</au><au>Rao, Yi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Interface Catalysts of Ni 3 Fe 1 Layered Double Hydroxide and Titanium Carbide for High-Performance Water Oxidation in Alkaline and Natural Conditions</atitle><jtitle>The journal of physical chemistry letters</jtitle><addtitle>J Phys Chem Lett</addtitle><date>2023-06-22</date><risdate>2023</risdate><volume>14</volume><issue>24</issue><spage>5692</spage><epage>5700</epage><pages>5692-5700</pages><issn>1948-7185</issn><eissn>1948-7185</eissn><abstract>The electrocatalytic oxygen evolution reaction (OER) is important for many renewable energy technologies. Developing cost-effective electrocatalysts with high performance remains a great challenge. Here, we successfully demonstrate our novel interface catalyst comprised of Ni
Fe
-based layered double hydroxides (Ni
Fe
-LDH) vertically immobilized on a two-dimensional MXene (Ti
C
T
) surface. The Ni
Fe
-LDH/Ti
C
T
yielded an anodic OER current of 100 mA cm
at 0.28 V versus reversible hydrogen electrode (RHE), nearly 74 times lower than that of the pristine Ni
Fe
-LDH. Furthermore, the Ni
Fe
-LDH/Ti
C
T
catalyst requires an overpotential of only 0.31 V versus RHE to deliver an industrial-level current density as high as 1000 mA cm
. Such excellent OER activity was attributed to the synergistic interface effect between Ni
Fe
-LDH and Ti
C
T
. Density functional theory (DFT) results further reveal that the Ti
C
T
support can efficiently accelerate the electron extraction from Ni
Fe
-LDH and tailor the electronic structure of catalytic sites, resulting in enhanced OER performance.</abstract><cop>United States</cop><pmid>37315210</pmid><doi>10.1021/acs.jpclett.3c00655</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0002-7801-4678</orcidid><orcidid>https://orcid.org/0000-0003-0790-5905</orcidid><orcidid>https://orcid.org/0000-0001-9882-1314</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1948-7185 |
| ispartof | The journal of physical chemistry letters, 2023-06, Vol.14 (24), p.5692-5700 |
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| language | eng |
| recordid | cdi_crossref_primary_10_1021_acs_jpclett_3c00655 |
| source | ACS Publications |
| title | Interface Catalysts of Ni 3 Fe 1 Layered Double Hydroxide and Titanium Carbide for High-Performance Water Oxidation in Alkaline and Natural Conditions |
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