Spectroscopic Identification of Transition-Metal M[η 2 -(O,O)C] Species for Highly-Efficient CO 2 Activation
The CO activation by transition metals is important in CO utilization but has proven to be challenging for experimental targets. Here we report first synthesis and spectroscopic characterization of transition-metal M[η -(O,O)C] species with bidentate double oxygen metal-CO coordination in the [ZrO(C...
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| Veröffentlicht in: | The journal of physical chemistry letters 2021-01, Vol.12 (1), p.472-477 |
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| container_title | The journal of physical chemistry letters |
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| creator | Zheng, Huijun Kong, Xiangtao Wang, Chong Wang, Tiantong Yang, Dong Li, Gang Xie, Hua Zhao, Zhi Shi, Ruili Han, Haiyan Fan, Hongjun Yang, Xueming Jiang, Ling |
| description | The CO
activation by transition metals is important in CO
utilization but has proven to be challenging for experimental targets. Here we report first synthesis and spectroscopic characterization of transition-metal M[η
-(O,O)C] species with bidentate double oxygen metal-CO
coordination in the [ZrO(CO
)
]
complexes. The Zr[η
-(O,O)C] species yields a CO
radical ligand, showing a high efficiency in CO
activation. We find that two important prerequisites are demanded for certain metals to form this intriguing M[η
-(O,O)C] species. One is that the metal center has high reduction capability, and the other is that the oxidation state of the metal center is lower than its highest one by 1. This study highlights the pivotal roles played by the M[η
-(O,O)C] species in CO
activation and also open new avenues toward the development of related single-atom catalysts with isolated transition-metal atoms dispersed on supports. |
| doi_str_mv | 10.1021/acs.jpclett.0c03379 |
| format | Article |
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activation by transition metals is important in CO
utilization but has proven to be challenging for experimental targets. Here we report first synthesis and spectroscopic characterization of transition-metal M[η
-(O,O)C] species with bidentate double oxygen metal-CO
coordination in the [ZrO(CO
)
]
complexes. The Zr[η
-(O,O)C] species yields a CO
radical ligand, showing a high efficiency in CO
activation. We find that two important prerequisites are demanded for certain metals to form this intriguing M[η
-(O,O)C] species. One is that the metal center has high reduction capability, and the other is that the oxidation state of the metal center is lower than its highest one by 1. This study highlights the pivotal roles played by the M[η
-(O,O)C] species in CO
activation and also open new avenues toward the development of related single-atom catalysts with isolated transition-metal atoms dispersed on supports.</description><identifier>ISSN: 1948-7185</identifier><identifier>EISSN: 1948-7185</identifier><identifier>DOI: 10.1021/acs.jpclett.0c03379</identifier><identifier>PMID: 33370117</identifier><language>eng</language><publisher>United States</publisher><ispartof>The journal of physical chemistry letters, 2021-01, Vol.12 (1), p.472-477</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1177-9fe3ded288c4623d8007631a63405acd1e6927cdc44efccdd31b9255ef173a843</citedby><cites>FETCH-LOGICAL-c1177-9fe3ded288c4623d8007631a63405acd1e6927cdc44efccdd31b9255ef173a843</cites><orcidid>0000-0003-2876-7580 ; 0000-0001-6684-9187 ; 0000-0002-8485-8893 ; 0000-0003-3406-6932 ; 0000-0003-2091-6457</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,2752,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/33370117$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Zheng, Huijun</creatorcontrib><creatorcontrib>Kong, Xiangtao</creatorcontrib><creatorcontrib>Wang, Chong</creatorcontrib><creatorcontrib>Wang, Tiantong</creatorcontrib><creatorcontrib>Yang, Dong</creatorcontrib><creatorcontrib>Li, Gang</creatorcontrib><creatorcontrib>Xie, Hua</creatorcontrib><creatorcontrib>Zhao, Zhi</creatorcontrib><creatorcontrib>Shi, Ruili</creatorcontrib><creatorcontrib>Han, Haiyan</creatorcontrib><creatorcontrib>Fan, Hongjun</creatorcontrib><creatorcontrib>Yang, Xueming</creatorcontrib><creatorcontrib>Jiang, Ling</creatorcontrib><title>Spectroscopic Identification of Transition-Metal M[η 2 -(O,O)C] Species for Highly-Efficient CO 2 Activation</title><title>The journal of physical chemistry letters</title><addtitle>J Phys Chem Lett</addtitle><description>The CO
activation by transition metals is important in CO
utilization but has proven to be challenging for experimental targets. Here we report first synthesis and spectroscopic characterization of transition-metal M[η
-(O,O)C] species with bidentate double oxygen metal-CO
coordination in the [ZrO(CO
)
]
complexes. The Zr[η
-(O,O)C] species yields a CO
radical ligand, showing a high efficiency in CO
activation. We find that two important prerequisites are demanded for certain metals to form this intriguing M[η
-(O,O)C] species. One is that the metal center has high reduction capability, and the other is that the oxidation state of the metal center is lower than its highest one by 1. This study highlights the pivotal roles played by the M[η
-(O,O)C] species in CO
activation and also open new avenues toward the development of related single-atom catalysts with isolated transition-metal atoms dispersed on supports.</description><issn>1948-7185</issn><issn>1948-7185</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpNkNFKwzAUhoMobk6fQJBcKtiZNG2TXo4y3WCjF84rkZKdJJrRraWJwp7Mt_CZzNwUr845cP6Pcz6ELikZUhLTOwluuGqh1t4PCRDGeH6E-jRPRMSpSI__9T105tyKkCwngp-iHgvLhFLeR-vHVoPvGgdNawFPld54ayxIb5sNbgxedHLj7G6K5trLGs-fvz5xjKPr8ra8KV7wDmC1w6bp8MS-vtXbaGwCwQYSLsqwOgJvP36A5-jEyNrpi0MdoKf78aKYRLPyYVqMZhGEo3iUG82UVrEQkGQxU4IQnjEqM5aQVIKiOstjDgqSRBsApRhd5nGaakM5kyJhA8T2XAifuU6bqu3sWnbbipJqJ68K8qqDvOogL6Su9qn2fbnW6i_za4t9A30obnU</recordid><startdate>20210114</startdate><enddate>20210114</enddate><creator>Zheng, Huijun</creator><creator>Kong, Xiangtao</creator><creator>Wang, Chong</creator><creator>Wang, Tiantong</creator><creator>Yang, Dong</creator><creator>Li, Gang</creator><creator>Xie, Hua</creator><creator>Zhao, Zhi</creator><creator>Shi, Ruili</creator><creator>Han, Haiyan</creator><creator>Fan, Hongjun</creator><creator>Yang, Xueming</creator><creator>Jiang, Ling</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-2876-7580</orcidid><orcidid>https://orcid.org/0000-0001-6684-9187</orcidid><orcidid>https://orcid.org/0000-0002-8485-8893</orcidid><orcidid>https://orcid.org/0000-0003-3406-6932</orcidid><orcidid>https://orcid.org/0000-0003-2091-6457</orcidid></search><sort><creationdate>20210114</creationdate><title>Spectroscopic Identification of Transition-Metal M[η 2 -(O,O)C] Species for Highly-Efficient CO 2 Activation</title><author>Zheng, Huijun ; Kong, Xiangtao ; Wang, Chong ; Wang, Tiantong ; Yang, Dong ; Li, Gang ; Xie, Hua ; Zhao, Zhi ; Shi, Ruili ; Han, Haiyan ; Fan, Hongjun ; Yang, Xueming ; Jiang, Ling</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1177-9fe3ded288c4623d8007631a63405acd1e6927cdc44efccdd31b9255ef173a843</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zheng, Huijun</creatorcontrib><creatorcontrib>Kong, Xiangtao</creatorcontrib><creatorcontrib>Wang, Chong</creatorcontrib><creatorcontrib>Wang, Tiantong</creatorcontrib><creatorcontrib>Yang, Dong</creatorcontrib><creatorcontrib>Li, Gang</creatorcontrib><creatorcontrib>Xie, Hua</creatorcontrib><creatorcontrib>Zhao, Zhi</creatorcontrib><creatorcontrib>Shi, Ruili</creatorcontrib><creatorcontrib>Han, Haiyan</creatorcontrib><creatorcontrib>Fan, Hongjun</creatorcontrib><creatorcontrib>Yang, Xueming</creatorcontrib><creatorcontrib>Jiang, Ling</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><jtitle>The journal of physical chemistry letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zheng, Huijun</au><au>Kong, Xiangtao</au><au>Wang, Chong</au><au>Wang, Tiantong</au><au>Yang, Dong</au><au>Li, Gang</au><au>Xie, Hua</au><au>Zhao, Zhi</au><au>Shi, Ruili</au><au>Han, Haiyan</au><au>Fan, Hongjun</au><au>Yang, Xueming</au><au>Jiang, Ling</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Spectroscopic Identification of Transition-Metal M[η 2 -(O,O)C] Species for Highly-Efficient CO 2 Activation</atitle><jtitle>The journal of physical chemistry letters</jtitle><addtitle>J Phys Chem Lett</addtitle><date>2021-01-14</date><risdate>2021</risdate><volume>12</volume><issue>1</issue><spage>472</spage><epage>477</epage><pages>472-477</pages><issn>1948-7185</issn><eissn>1948-7185</eissn><abstract>The CO
activation by transition metals is important in CO
utilization but has proven to be challenging for experimental targets. Here we report first synthesis and spectroscopic characterization of transition-metal M[η
-(O,O)C] species with bidentate double oxygen metal-CO
coordination in the [ZrO(CO
)
]
complexes. The Zr[η
-(O,O)C] species yields a CO
radical ligand, showing a high efficiency in CO
activation. We find that two important prerequisites are demanded for certain metals to form this intriguing M[η
-(O,O)C] species. One is that the metal center has high reduction capability, and the other is that the oxidation state of the metal center is lower than its highest one by 1. This study highlights the pivotal roles played by the M[η
-(O,O)C] species in CO
activation and also open new avenues toward the development of related single-atom catalysts with isolated transition-metal atoms dispersed on supports.</abstract><cop>United States</cop><pmid>33370117</pmid><doi>10.1021/acs.jpclett.0c03379</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0003-2876-7580</orcidid><orcidid>https://orcid.org/0000-0001-6684-9187</orcidid><orcidid>https://orcid.org/0000-0002-8485-8893</orcidid><orcidid>https://orcid.org/0000-0003-3406-6932</orcidid><orcidid>https://orcid.org/0000-0003-2091-6457</orcidid></addata></record> |
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| source | American Chemical Society |
| title | Spectroscopic Identification of Transition-Metal M[η 2 -(O,O)C] Species for Highly-Efficient CO 2 Activation |
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