Direct Observation of Phenoxy as the Key and Common Intermediate for the Decomposition of Lignin Fragments Containing the β‑O‑4 Linkage

The decomposition of phenol, anisole, and 2-phenoxyethanol on Pt(111) in ultrahigh vacuum is studied as a model to understand the reactivity of the β-O-4 linkage in lignin. Desorption of the multilayer and monolayer is observed as well as the generation of decomposition products. Using RAIRS to moni...

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Veröffentlicht in:	Journal of physical chemistry. C 2019-04, Vol.123 (13), p.8122-8132
Hauptverfasser:	Ould Hamou, Cherif A, Giorgi, Javier B
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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