Effect of Surface Diffusion on Adsorption–Desorption and Catalytic Kinetics in Irregular Pores. I. Local Kinetics

By using a mass balance equation, we deduce an effective equation for the concentration of adsorbed particles that considers the surface diffusion of the particles and an adsorption–desorption process inside a pore of irregular shape. This equation, together with the generalized Fick–Jacobs equation...

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Veröffentlicht in:Journal of physical chemistry. C 2017-07, Vol.121 (27), p.14544-14556
Hauptverfasser: Ledesma-Durán, Aldo, Hernández, S. I, Santamaría-Holek, Iván
Format: Artikel
Sprache:eng
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