Charge-Transfer Complexes of Benzothienobenzothiophene with Tetracyanoquinodimethane and the n‑Channel Organic Field-Effect Transistors

Charge-Transfer Complexes of Benzothienobenzothiophene with Tetracyanoquinodimethane and the n‑Channel Organic Field-Effect Transistors

n-Channel organic transistors with excellent air stability are realized on the basis of charge-transfer complexes, (BTBT)­(TCNQ), (BTBT)­(F2TCNQ), (BSBS)­(F2TCNQ), and (BTBT)­(F4TCNQ), where BTBT is benzothieno­[3,2-b]­benzo­thiophene, BSBS is benzo­seleno­[3,2-b]­benzo­selenophene, and F n TCNQ (n...

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Veröffentlicht in:Journal of physical chemistry. C 2017-03, Vol.121 (12), p.6561-6568
Hauptverfasser: Sato, Ryonosuke, Dogishi, Masaki, Higashino, Toshiki, Kadoya, Tomofumi, Kawamoto, Tadashi, Mori, Takehiko
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container_end_page 6568
container_issue 12
container_start_page 6561
container_title Journal of physical chemistry. C
container_volume 121
creator Sato, Ryonosuke
Dogishi, Masaki
Higashino, Toshiki
Kadoya, Tomofumi
Kawamoto, Tadashi
Mori, Takehiko
description n-Channel organic transistors with excellent air stability are realized on the basis of charge-transfer complexes, (BTBT)­(TCNQ), (BTBT)­(F2TCNQ), (BSBS)­(F2TCNQ), and (BTBT)­(F4TCNQ), where BTBT is benzothieno­[3,2-b]­benzo­thiophene, BSBS is benzo­seleno­[3,2-b]­benzo­selenophene, and F n TCNQ (n = 0, 2, and 4) are fluorinated 7,7,8,8-tetracyanoquinodimethanes. These complexes consist of mixed stacks of essentially neutral molecules, and the transistors are air stable even after several-month storage in ambient conditions.
doi_str_mv 10.1021/acs.jpcc.7b00902
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title Charge-Transfer Complexes of Benzothienobenzothiophene with Tetracyanoquinodimethane and the n‑Channel Organic Field-Effect Transistors
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