Dynamics and Thermodynamics of Pd–PdO Phase Transitions: Effects of Pd Cluster Size and Kinetic Implications for Catalytic Methane Combustion

Methane oxidation rates uncorrupted by nonchemical effects of transport, taken together with stoichiometric oxygen uptake (oxidation cycle) and evolution (decomposition cycle) data, are used to establish for the first time a set of conditions required for true thermodynamic equilibrium during metal-...

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Veröffentlicht in:	Journal of physical chemistry. C 2016-01, Vol.120 (3), p.1446-1460
Hauptverfasser:	Chin, Ya-Huei (Cathy), García-Diéguez, Mónica, Iglesia, Enrique
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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