Updatable Holographic Diffraction of Monolithic Carbazole-Azobenzene Compound in Poly(methyl methacrylate) Matrix
The comprehensive mechanism of updatable holographic diffraction is presented for a monolithic compound of 3-[(4-nitrophenyl)azo]-9H-carbazole-9-ethanol (NACzE) dispersed poly(methyl methacrylate) film device. The maximum sensitivity occurs at 561 nm, which well coincides with an isosbestic point...
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| Veröffentlicht in: | Journal of physical chemistry. C 2015-08, Vol.119 (32), p.18567-18572 |
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| container_end_page | 18572 |
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| container_issue | 32 |
| container_start_page | 18567 |
| container_title | Journal of physical chemistry. C |
| container_volume | 119 |
| creator | Tsutsumi, Naoto Kinashi, Kenji Ogo, Kanako Fukami, Takahiro Yabuhara, Yuuki Kawabe, Yutaka Tada, Kazuhiro Fukuzawa, Kodai Kawamoto, Masuki Sassa, Takafumi Fujihara, Takashi Sasaki, Takeo Naka, Yumiko |
| description | The comprehensive mechanism of updatable holographic diffraction is presented for a monolithic compound of 3-[(4-nitrophenyl)azo]-9H-carbazole-9-ethanol (NACzE) dispersed poly(methyl methacrylate) film device. The maximum sensitivity occurs at 561 nm, which well coincides with an isosbestic point between cis-trans isomers of NACzE molecule. The holographic grating is ascribed to the absorption grating and the following refractive index grating due to the photo-orientation of NACzE molecules. The response and decay times for the diffraction are governed by the glass transition temperature of the matrix. |
| doi_str_mv | 10.1021/acs.jpcc.5b04869 |
| format | Article |
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C</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tsutsumi, Naoto</au><au>Kinashi, Kenji</au><au>Ogo, Kanako</au><au>Fukami, Takahiro</au><au>Yabuhara, Yuuki</au><au>Kawabe, Yutaka</au><au>Tada, Kazuhiro</au><au>Fukuzawa, Kodai</au><au>Kawamoto, Masuki</au><au>Sassa, Takafumi</au><au>Fujihara, Takashi</au><au>Sasaki, Takeo</au><au>Naka, Yumiko</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Updatable Holographic Diffraction of Monolithic Carbazole-Azobenzene Compound in Poly(methyl methacrylate) Matrix</atitle><jtitle>Journal of physical chemistry. C</jtitle><addtitle>J. Phys. Chem. 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| source | ACS Publications |
| title | Updatable Holographic Diffraction of Monolithic Carbazole-Azobenzene Compound in Poly(methyl methacrylate) Matrix |
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