Supramolecular Anisotropy in a Surface-Confined Bicomponent System

Anisotropical engineering of surface-confined supramolecules provides a potential approach to precisely tweaking the properties and performance of low-dimensional molecular nanomaterials. Here, we report the construction of a surface-confined bicomponent supramolecular structure that features struct...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of physical chemistry. C 2022-12, Vol.126 (48), p.20739-20746
Hauptverfasser: Wen, Xiaojie, Li, Jie, Lin, Yuxuan, Diao, Mengxiao, Zhao, Wenhui, Di, Bin, Peng, Zhantao, Liu, Dan, Zhou, Xiong, Chen, Qiwei, Wang, Yongfeng, Liu, Jing, Wu, Kai
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 20746
container_issue 48
container_start_page 20739
container_title Journal of physical chemistry. C
container_volume 126
creator Wen, Xiaojie
Li, Jie
Lin, Yuxuan
Diao, Mengxiao
Zhao, Wenhui
Di, Bin
Peng, Zhantao
Liu, Dan
Zhou, Xiong
Chen, Qiwei
Wang, Yongfeng
Liu, Jing
Wu, Kai
description Anisotropical engineering of surface-confined supramolecules provides a potential approach to precisely tweaking the properties and performance of low-dimensional molecular nanomaterials. Here, we report the construction of a surface-confined bicomponent supramolecular structure that features structural anisotropy by combined scanning tunneling microscopy and density functional theory studies. One-dimensional supramolecular ribbons formed by corannulene with either titanyl phthalocyanine or copper phthalocyanine exclusively extend along the equivalent ⟨11̅0⟩ directions on Ag(111). Such a supramolecular anisotropy is demonstrated as a result of the combined effects of molecule–substrate commensurability and intermolecular interaction relaxation, which leads to orientation-dependent energy cost for commensurate growth of the supramolecular ribbon on Ag(111). These findings provide insights into the mediation effect of the fine balance between the molecule–substrate and intermolecular interactions on the supramolecular structures, offering an efficient methodology for supramolecular anisotropical engineering.
doi_str_mv 10.1021/acs.jpcc.2c07707
format Article
fullrecord <record><control><sourceid>acs_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1021_acs_jpcc_2c07707</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>e83703259</sourcerecordid><originalsourceid>FETCH-LOGICAL-a233t-4917351fa329b4b55d3c58bbacf32f12723a7ffec76a744698353c3198db1003</originalsourceid><addsrcrecordid>eNp1kM1qwzAQhEVpoWnae496gNqVtFZkH5PQPwj04NzNWpbAwZaMZB_89nWa0FtPszAzy_AR8sxZypngr6hjehq0ToVmSjF1Q1a8AJGoTMrbvztT9-QhxhNjEhiHFdmV0xCw953RU4eBbl0b_Rj8MNPWUaTlFCxqk-y9s60zDd212veDd8aNtJzjaPpHcmexi-bpqmtyfH877j-Tw_fH1357SFAAjElWcAWSWwRR1FktZQNa5nWN2oKwXCgBqKw1Wm1wGbopcpCggRd5U3PGYE3Y5a0OPsZgbDWEtscwV5xVZwTVgqA6I6iuCJbKy6Xy6_gpuGXf__EfQ7Nf4g</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Supramolecular Anisotropy in a Surface-Confined Bicomponent System</title><source>American Chemical Society Journals</source><creator>Wen, Xiaojie ; Li, Jie ; Lin, Yuxuan ; Diao, Mengxiao ; Zhao, Wenhui ; Di, Bin ; Peng, Zhantao ; Liu, Dan ; Zhou, Xiong ; Chen, Qiwei ; Wang, Yongfeng ; Liu, Jing ; Wu, Kai</creator><creatorcontrib>Wen, Xiaojie ; Li, Jie ; Lin, Yuxuan ; Diao, Mengxiao ; Zhao, Wenhui ; Di, Bin ; Peng, Zhantao ; Liu, Dan ; Zhou, Xiong ; Chen, Qiwei ; Wang, Yongfeng ; Liu, Jing ; Wu, Kai</creatorcontrib><description>Anisotropical engineering of surface-confined supramolecules provides a potential approach to precisely tweaking the properties and performance of low-dimensional molecular nanomaterials. Here, we report the construction of a surface-confined bicomponent supramolecular structure that features structural anisotropy by combined scanning tunneling microscopy and density functional theory studies. One-dimensional supramolecular ribbons formed by corannulene with either titanyl phthalocyanine or copper phthalocyanine exclusively extend along the equivalent ⟨11̅0⟩ directions on Ag(111). Such a supramolecular anisotropy is demonstrated as a result of the combined effects of molecule–substrate commensurability and intermolecular interaction relaxation, which leads to orientation-dependent energy cost for commensurate growth of the supramolecular ribbon on Ag(111). These findings provide insights into the mediation effect of the fine balance between the molecule–substrate and intermolecular interactions on the supramolecular structures, offering an efficient methodology for supramolecular anisotropical engineering.</description><identifier>ISSN: 1932-7447</identifier><identifier>EISSN: 1932-7455</identifier><identifier>DOI: 10.1021/acs.jpcc.2c07707</identifier><language>eng</language><publisher>American Chemical Society</publisher><subject>C: Physical Properties of Materials and Interfaces</subject><ispartof>Journal of physical chemistry. C, 2022-12, Vol.126 (48), p.20739-20746</ispartof><rights>2022 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-a233t-4917351fa329b4b55d3c58bbacf32f12723a7ffec76a744698353c3198db1003</cites><orcidid>0000-0002-5016-0251 ; 0000-0002-8990-5783 ; 0000-0002-8171-3189 ; 0000-0002-8120-7147 ; 0000-0003-2713-9072 ; 0000-0002-2948-5035 ; 0000-0001-9629-387X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acs.jpcc.2c07707$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acs.jpcc.2c07707$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2765,27076,27924,27925,56738,56788</link.rule.ids></links><search><creatorcontrib>Wen, Xiaojie</creatorcontrib><creatorcontrib>Li, Jie</creatorcontrib><creatorcontrib>Lin, Yuxuan</creatorcontrib><creatorcontrib>Diao, Mengxiao</creatorcontrib><creatorcontrib>Zhao, Wenhui</creatorcontrib><creatorcontrib>Di, Bin</creatorcontrib><creatorcontrib>Peng, Zhantao</creatorcontrib><creatorcontrib>Liu, Dan</creatorcontrib><creatorcontrib>Zhou, Xiong</creatorcontrib><creatorcontrib>Chen, Qiwei</creatorcontrib><creatorcontrib>Wang, Yongfeng</creatorcontrib><creatorcontrib>Liu, Jing</creatorcontrib><creatorcontrib>Wu, Kai</creatorcontrib><title>Supramolecular Anisotropy in a Surface-Confined Bicomponent System</title><title>Journal of physical chemistry. C</title><addtitle>J. Phys. Chem. C</addtitle><description>Anisotropical engineering of surface-confined supramolecules provides a potential approach to precisely tweaking the properties and performance of low-dimensional molecular nanomaterials. Here, we report the construction of a surface-confined bicomponent supramolecular structure that features structural anisotropy by combined scanning tunneling microscopy and density functional theory studies. One-dimensional supramolecular ribbons formed by corannulene with either titanyl phthalocyanine or copper phthalocyanine exclusively extend along the equivalent ⟨11̅0⟩ directions on Ag(111). Such a supramolecular anisotropy is demonstrated as a result of the combined effects of molecule–substrate commensurability and intermolecular interaction relaxation, which leads to orientation-dependent energy cost for commensurate growth of the supramolecular ribbon on Ag(111). These findings provide insights into the mediation effect of the fine balance between the molecule–substrate and intermolecular interactions on the supramolecular structures, offering an efficient methodology for supramolecular anisotropical engineering.</description><subject>C: Physical Properties of Materials and Interfaces</subject><issn>1932-7447</issn><issn>1932-7455</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1kM1qwzAQhEVpoWnae496gNqVtFZkH5PQPwj04NzNWpbAwZaMZB_89nWa0FtPszAzy_AR8sxZypngr6hjehq0ToVmSjF1Q1a8AJGoTMrbvztT9-QhxhNjEhiHFdmV0xCw953RU4eBbl0b_Rj8MNPWUaTlFCxqk-y9s60zDd212veDd8aNtJzjaPpHcmexi-bpqmtyfH877j-Tw_fH1357SFAAjElWcAWSWwRR1FktZQNa5nWN2oKwXCgBqKw1Wm1wGbopcpCggRd5U3PGYE3Y5a0OPsZgbDWEtscwV5xVZwTVgqA6I6iuCJbKy6Xy6_gpuGXf__EfQ7Nf4g</recordid><startdate>20221208</startdate><enddate>20221208</enddate><creator>Wen, Xiaojie</creator><creator>Li, Jie</creator><creator>Lin, Yuxuan</creator><creator>Diao, Mengxiao</creator><creator>Zhao, Wenhui</creator><creator>Di, Bin</creator><creator>Peng, Zhantao</creator><creator>Liu, Dan</creator><creator>Zhou, Xiong</creator><creator>Chen, Qiwei</creator><creator>Wang, Yongfeng</creator><creator>Liu, Jing</creator><creator>Wu, Kai</creator><general>American Chemical Society</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-5016-0251</orcidid><orcidid>https://orcid.org/0000-0002-8990-5783</orcidid><orcidid>https://orcid.org/0000-0002-8171-3189</orcidid><orcidid>https://orcid.org/0000-0002-8120-7147</orcidid><orcidid>https://orcid.org/0000-0003-2713-9072</orcidid><orcidid>https://orcid.org/0000-0002-2948-5035</orcidid><orcidid>https://orcid.org/0000-0001-9629-387X</orcidid></search><sort><creationdate>20221208</creationdate><title>Supramolecular Anisotropy in a Surface-Confined Bicomponent System</title><author>Wen, Xiaojie ; Li, Jie ; Lin, Yuxuan ; Diao, Mengxiao ; Zhao, Wenhui ; Di, Bin ; Peng, Zhantao ; Liu, Dan ; Zhou, Xiong ; Chen, Qiwei ; Wang, Yongfeng ; Liu, Jing ; Wu, Kai</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a233t-4917351fa329b4b55d3c58bbacf32f12723a7ffec76a744698353c3198db1003</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>C: Physical Properties of Materials and Interfaces</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wen, Xiaojie</creatorcontrib><creatorcontrib>Li, Jie</creatorcontrib><creatorcontrib>Lin, Yuxuan</creatorcontrib><creatorcontrib>Diao, Mengxiao</creatorcontrib><creatorcontrib>Zhao, Wenhui</creatorcontrib><creatorcontrib>Di, Bin</creatorcontrib><creatorcontrib>Peng, Zhantao</creatorcontrib><creatorcontrib>Liu, Dan</creatorcontrib><creatorcontrib>Zhou, Xiong</creatorcontrib><creatorcontrib>Chen, Qiwei</creatorcontrib><creatorcontrib>Wang, Yongfeng</creatorcontrib><creatorcontrib>Liu, Jing</creatorcontrib><creatorcontrib>Wu, Kai</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of physical chemistry. C</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wen, Xiaojie</au><au>Li, Jie</au><au>Lin, Yuxuan</au><au>Diao, Mengxiao</au><au>Zhao, Wenhui</au><au>Di, Bin</au><au>Peng, Zhantao</au><au>Liu, Dan</au><au>Zhou, Xiong</au><au>Chen, Qiwei</au><au>Wang, Yongfeng</au><au>Liu, Jing</au><au>Wu, Kai</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Supramolecular Anisotropy in a Surface-Confined Bicomponent System</atitle><jtitle>Journal of physical chemistry. C</jtitle><addtitle>J. Phys. Chem. C</addtitle><date>2022-12-08</date><risdate>2022</risdate><volume>126</volume><issue>48</issue><spage>20739</spage><epage>20746</epage><pages>20739-20746</pages><issn>1932-7447</issn><eissn>1932-7455</eissn><abstract>Anisotropical engineering of surface-confined supramolecules provides a potential approach to precisely tweaking the properties and performance of low-dimensional molecular nanomaterials. Here, we report the construction of a surface-confined bicomponent supramolecular structure that features structural anisotropy by combined scanning tunneling microscopy and density functional theory studies. One-dimensional supramolecular ribbons formed by corannulene with either titanyl phthalocyanine or copper phthalocyanine exclusively extend along the equivalent ⟨11̅0⟩ directions on Ag(111). Such a supramolecular anisotropy is demonstrated as a result of the combined effects of molecule–substrate commensurability and intermolecular interaction relaxation, which leads to orientation-dependent energy cost for commensurate growth of the supramolecular ribbon on Ag(111). These findings provide insights into the mediation effect of the fine balance between the molecule–substrate and intermolecular interactions on the supramolecular structures, offering an efficient methodology for supramolecular anisotropical engineering.</abstract><pub>American Chemical Society</pub><doi>10.1021/acs.jpcc.2c07707</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-5016-0251</orcidid><orcidid>https://orcid.org/0000-0002-8990-5783</orcidid><orcidid>https://orcid.org/0000-0002-8171-3189</orcidid><orcidid>https://orcid.org/0000-0002-8120-7147</orcidid><orcidid>https://orcid.org/0000-0003-2713-9072</orcidid><orcidid>https://orcid.org/0000-0002-2948-5035</orcidid><orcidid>https://orcid.org/0000-0001-9629-387X</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 1932-7447
ispartof Journal of physical chemistry. C, 2022-12, Vol.126 (48), p.20739-20746
issn 1932-7447
1932-7455
language eng
recordid cdi_crossref_primary_10_1021_acs_jpcc_2c07707
source American Chemical Society Journals
subjects C: Physical Properties of Materials and Interfaces
title Supramolecular Anisotropy in a Surface-Confined Bicomponent System
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-24T15%3A08%3A51IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Supramolecular%20Anisotropy%20in%20a%20Surface-Confined%20Bicomponent%20System&rft.jtitle=Journal%20of%20physical%20chemistry.%20C&rft.au=Wen,%20Xiaojie&rft.date=2022-12-08&rft.volume=126&rft.issue=48&rft.spage=20739&rft.epage=20746&rft.pages=20739-20746&rft.issn=1932-7447&rft.eissn=1932-7455&rft_id=info:doi/10.1021/acs.jpcc.2c07707&rft_dat=%3Cacs_cross%3Ee83703259%3C/acs_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true