Mechanistic Insight into Formic Acid/Formate Oxidation at the Au(111) Electrode: Implications from the pH Effect and H/D Kinetic Isotope Effect

Formate adsorption and formic acid oxidation reaction (FAOR) on Au(111) in solutions with 0 < pH < 14 with either HCOOH/HCOO– or DCOOH/DCOO– as precursors have been systematically investigated by cyclic voltammetry. The results are analyzed with the help of computer simulation and careful comp...

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Veröffentlicht in:	Journal of physical chemistry. C 2022-07, Vol.126 (29), p.11987-12002
Hauptverfasser:	Wei, Zhen, Zhang, Meng Ke, Zhu, Bai Quan, Cai, Jun, Chen, Yan-Xia
Format:	Artikel
Sprache:	eng
Schlagworte:	C: Chemical and Catalytic Reactivity at Interfaces
Online-Zugang:	Volltext
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