Nature of the Surface Intermediates Formed from Methane on Cu-ZSM‑5 Zeolite: A Combined Solid-State Nuclear Magnetic Resonance and Density Functional Theory Study

The intermediates formed upon the interaction of methane with Cu-modified ZSM-5 zeolites (Cu/H-ZSM-5) have been analyzed with solid-state NMR spectroscopy and DFT methods. Methane activation by Cu/H-ZSM-5 zeolites gives rise to three distinct surface methoxy-like species (−O–CH3) detected by 13C MAS...

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Veröffentlicht in:	Journal of physical chemistry. C 2020-03, Vol.124 (11), p.6242-6252
Hauptverfasser:	Kolganov, Alexander A, Gabrienko, Anton A, Yashnik, Svetlana A, Pidko, Evgeny A, Stepanov, Alexander G
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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