Differential Dynamics at Glycosidic Linkages of an Oligosaccharide as Revealed by 13 C NMR Spin Relaxation and Stochastic Modeling

Among biomolecules, carbohydrates are unique in that not only can linkages be formed through different positions, but the structures may also be branched. The trisaccharide β-d-Glcp-(1→3)[β-d-Glcp-(1→2)]-α-d-Manp-OMe represents a model of a branched vicinally disubstituted structure. A C site-specif...

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Veröffentlicht in:The journal of physical chemistry. B 2018-03, Vol.122 (8), p.2287-2294
Hauptverfasser: Zerbetto, Mirco, Angles d'Ortoli, Thibault, Polimeno, Antonino, Widmalm, Göran
Format: Artikel
Sprache:eng
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