BrHgO • + C 2 H 4 and BrHgO • + HCHO in Atmospheric Oxidation of Mercury: Determining Rate Constants of Reactions with Prereactive Complexes and Bifurcation

Models suggest BrHgONO to be the major Hg(II) species formed in the global oxidation of Hg(0), and BrHgONO undergoes rapid photolysis to produce the thermally stable radical BrHgO . We previously used quantum chemistry to demonstrate that BrHgO can, like OH radicals, readily abstract hydrogen atoms...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2019-07, Vol.123 (28), p.6045-6055
Hauptverfasser:	Lam, Khoa T, Wilhelmsen, Curtis J, Dibble, Theodore S
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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