Cerium Cation (Ce + ) Reactions with H 2 , D 2 , and HD: CeH + Bond Energy and Mechanistic Insights from Guided Ion Beam and Theoretical Studies

Reactions of the atomic lanthanide cerium cation (Ce ) with H , D , and HD were studied by using guided ion beam tandem mass spectrometry. Analysis of the kinetic-energy-dependent endothermic reactions to form CeH (CeD ) led to a 0 K bond dissociation energy (BDE) for CeH of 2.19 ± 0.09 eV. Theoreti...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2020-04, Vol.124 (13), p.2560-2572
Hauptverfasser:	Ghiassee, Maryam, Armentrout, P B
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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