Synthesis and Electrochemical Properties of Fullerenylstyrenes

Synthesis and Electrochemical Properties of Fullerenylstyrenes

An efficient preparative method was developed for the synthesis of previously unreported fullerenylstyrenes based on the reaction of C60 fullerene with terminal acetylenes and EtMgBr in the presence of Ti­(Oi-Pr)4. The voltammetric curves of the prepared fullerenylstyrenes were studied, and good pro...

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Veröffentlicht in:Journal of organic chemistry 2019-12, Vol.84 (24), p.16333-16337
Hauptverfasser: Tuktarov, Airat R, Chobanov, Nuri M, Budnikova, Yulia H, Dudkina, Yulia B, Dzhemilev, Usein M
Format: Artikel
Sprache:eng
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Zusammenfassung:An efficient preparative method was developed for the synthesis of previously unreported fullerenylstyrenes based on the reaction of C60 fullerene with terminal acetylenes and EtMgBr in the presence of Ti­(Oi-Pr)4. The voltammetric curves of the prepared fullerenylstyrenes were studied, and good prospects for their application as acceptor materials for bulk heterojunction solar cell were demonstrated.
ISSN:0022-3263
1520-6904
DOI:10.1021/acs.joc.9b02728