Selective, Scalable Synthesis of C 60 -Fullerene/Indene Monoadducts Using a Microwave Flow Applicator

Selective, Scalable Synthesis of C 60 -Fullerene/Indene Monoadducts Using a Microwave Flow Applicator

The synergy of continuous processing and microwave heating technologies has unlocked scalable (g/h), safe and efficient reaction conditions for synthesis of fullerene/indene-based organic photovoltaic acceptor materials in a nonchlorinated solvent with levels of productivity unparalleled by previous...

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Veröffentlicht in:Journal of organic chemistry 2018-04, Vol.83 (8), p.4348-4354
Hauptverfasser: Barham, Joshua P, Tanaka, Satoko, Koyama, Emiko, Ohneda, Noriyuki, Okamoto, Tadashi, Odajima, Hiromichi, Sugiyama, Jun-Ichi, Norikane, Yasuo
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container_end_page 4354
container_issue 8
container_start_page 4348
container_title Journal of organic chemistry
container_volume 83
creator Barham, Joshua P
Tanaka, Satoko
Koyama, Emiko
Ohneda, Noriyuki
Okamoto, Tadashi
Odajima, Hiromichi
Sugiyama, Jun-Ichi
Norikane, Yasuo
description The synergy of continuous processing and microwave heating technologies has unlocked scalable (g/h), safe and efficient reaction conditions for synthesis of fullerene/indene-based organic photovoltaic acceptor materials in a nonchlorinated solvent with levels of productivity unparalleled by previous syntheses. The microwave flow reactor sustains high temperature while employing short residence times, reaction conditions which uniquely allow the selective synthesis of fullerene/indene monoadducts. Design of experiments analysis revealed residence time as the most crucial factor for conversion and selectivity control.
doi_str_mv 10.1021/acs.joc.7b03209
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title Selective, Scalable Synthesis of C 60 -Fullerene/Indene Monoadducts Using a Microwave Flow Applicator
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