Novel Carbonothioate-Based Colorimetric and Fluorescent Probe for Selective Detection of Mercury Ions

Novel Carbonothioate-Based Colorimetric and Fluorescent Probe for Selective Detection of Mercury Ions

The development of probes for selective detection of mercury ions (Hg2+) is an important mission to accomplish because of the toxicity and ubiquity of Hg2+. Herein, we designed and synthesized a novel fluorescent probe O-(N-butyl-1,8-naphthalimide)-4-yl-O-phenyl carbonothioate (CBONT) for selective...

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Veröffentlicht in:Industrial & engineering chemistry research 2016-08, Vol.55 (32), p.8713-8718
Hauptverfasser: Shu, Wei, Wang, Yawei, Wu, Liu, Wang, Zuokai, Duan, Qingxia, Gao, Yibo, Liu, Caiyun, Zhu, Baocun, Yan, Liangguo
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container_end_page 8718
container_issue 32
container_start_page 8713
container_title Industrial & engineering chemistry research
container_volume 55
creator Shu, Wei
Wang, Yawei
Wu, Liu
Wang, Zuokai
Duan, Qingxia
Gao, Yibo
Liu, Caiyun
Zhu, Baocun
Yan, Liangguo
description The development of probes for selective detection of mercury ions (Hg2+) is an important mission to accomplish because of the toxicity and ubiquity of Hg2+. Herein, we designed and synthesized a novel fluorescent probe O-(N-butyl-1,8-naphthalimide)-4-yl-O-phenyl carbonothioate (CBONT) for selective and sensitive detection of Hg2+ by turn-on fluorescence spectroscopy. Probe CBONT exhibited a fast response for Hg2+ with excellent sensitivity (limit of detection = 1.9 nM, 3σ/slope), and it might be attributed to the adoption of a new recognition receptor of carbonothioate moiety. Additionally, probe CBONT could serve as a “naked-eye” indicator for Hg2+. Finally, probe CBONT could be successfully applied to detect the concentrations of Hg2+ in real water samples. Our proposed recognition receptor would open up new, exciting opportunities for designing highly selective and ultrasensitive fluorescent probes for the determination of Hg2+ in real water samples.
doi_str_mv 10.1021/acs.iecr.6b02158
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title Novel Carbonothioate-Based Colorimetric and Fluorescent Probe for Selective Detection of Mercury Ions
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