Ionic Liquid as a Catalyst toward NIPU via a Microwave Radiation Process
In this work, catalytic and microwave intensification effects on the ring-opening reaction between butanediol bicyclic carbonates and Jeffamine D230 were investigated. It was found that tetrabutyl methyl carbonate has perfect catalytic effects compared to conventional catalysts such as lithium bromi...
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| Veröffentlicht in: | Industrial & engineering chemistry research 2024-10, Vol.63 (41), p.17430-17440 |
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| container_issue | 41 |
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| container_title | Industrial & engineering chemistry research |
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| creator | Yang, Ping-Lin Tsai, Sung-Han Han, Yao-Yi Chao, Hsien-Wen Chen, Kan-Nan Wong, David Shan-Hill |
| description | In this work, catalytic and microwave intensification effects on the ring-opening reaction between butanediol bicyclic carbonates and Jeffamine D230 were investigated. It was found that tetrabutyl methyl carbonate has perfect catalytic effects compared to conventional catalysts such as lithium bromide and can be substantially intensified by microwave heating and flow chemistry. The ionic liquid can be easily recovered from the product by using water washing and reused with little decay in reactivity. These results represent significant opportunities for the development of a green and sustainable route of nonisocyanate polyurethane. |
| doi_str_mv | 10.1021/acs.iecr.4c00510 |
| format | Article |
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It was found that tetrabutyl methyl carbonate has perfect catalytic effects compared to conventional catalysts such as lithium bromide and can be substantially intensified by microwave heating and flow chemistry. The ionic liquid can be easily recovered from the product by using water washing and reused with little decay in reactivity. These results represent significant opportunities for the development of a green and sustainable route of nonisocyanate polyurethane.</description><identifier>ISSN: 0888-5885</identifier><identifier>ISSN: 1520-5045</identifier><identifier>EISSN: 1520-5045</identifier><identifier>DOI: 10.1021/acs.iecr.4c00510</identifier><language>eng</language><publisher>American Chemical Society</publisher><subject>Applied Chemistry ; butanediol ; carbonates ; catalysts ; chemistry ; ionic liquids ; lithium ; microwave radiation ; microwave treatment ; polyurethanes</subject><ispartof>Industrial & engineering chemistry research, 2024-10, Vol.63 (41), p.17430-17440</ispartof><rights>2024 The Authors. 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Eng. Chem. Res</addtitle><description>In this work, catalytic and microwave intensification effects on the ring-opening reaction between butanediol bicyclic carbonates and Jeffamine D230 were investigated. It was found that tetrabutyl methyl carbonate has perfect catalytic effects compared to conventional catalysts such as lithium bromide and can be substantially intensified by microwave heating and flow chemistry. The ionic liquid can be easily recovered from the product by using water washing and reused with little decay in reactivity. These results represent significant opportunities for the development of a green and sustainable route of nonisocyanate polyurethane.</description><subject>Applied Chemistry</subject><subject>butanediol</subject><subject>carbonates</subject><subject>catalysts</subject><subject>chemistry</subject><subject>ionic liquids</subject><subject>lithium</subject><subject>microwave radiation</subject><subject>microwave treatment</subject><subject>polyurethanes</subject><issn>0888-5885</issn><issn>1520-5045</issn><issn>1520-5045</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp1kDFPwzAQhS0EEqWwM3pkIMWOfYkzogpopQIVorNlO1fJVZq0dgLqv8dVuzKddO97p3uPkHvOJpzl_Mm4OPHowkQ6xoCzCzLikLMMmIRLMmJKqQyUgmtyE-OGJQakHJHZvGu9owu_H3xNTaSGTk1vmkPsad_9mlDTj_lyRX-8SdK7dyEtf5B-mdqb3nctXYbOYYy35Gptmoh35zkmq9eX7-ksW3y-zafPi8zkQvVZUZVW5lYJllvEIkerKitBCVs65CVCbaSyWFS8LEQFINZWQFWUUgIXsi7EmDyc7u5Ctx8w9nrro8OmMS12Q9SCg1AypS4Tyk5oejrGgGu9C35rwkFzpo-l6VSaPpamz6Uly-PJclQ23RDalOV__A8rTG4x</recordid><startdate>20241008</startdate><enddate>20241008</enddate><creator>Yang, Ping-Lin</creator><creator>Tsai, Sung-Han</creator><creator>Han, Yao-Yi</creator><creator>Chao, Hsien-Wen</creator><creator>Chen, Kan-Nan</creator><creator>Wong, David Shan-Hill</creator><general>American Chemical Society</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7S9</scope><scope>L.6</scope><orcidid>https://orcid.org/0009-0009-5026-0162</orcidid><orcidid>https://orcid.org/0000-0001-8574-8234</orcidid></search><sort><creationdate>20241008</creationdate><title>Ionic Liquid as a Catalyst toward NIPU via a Microwave Radiation Process</title><author>Yang, Ping-Lin ; Tsai, Sung-Han ; Han, Yao-Yi ; Chao, Hsien-Wen ; Chen, Kan-Nan ; Wong, David Shan-Hill</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a238t-697b42b8302bee62eb89b4583b7ce17e5da48be6917639553fb35967445134d63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Applied Chemistry</topic><topic>butanediol</topic><topic>carbonates</topic><topic>catalysts</topic><topic>chemistry</topic><topic>ionic liquids</topic><topic>lithium</topic><topic>microwave radiation</topic><topic>microwave treatment</topic><topic>polyurethanes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yang, Ping-Lin</creatorcontrib><creatorcontrib>Tsai, Sung-Han</creatorcontrib><creatorcontrib>Han, Yao-Yi</creatorcontrib><creatorcontrib>Chao, Hsien-Wen</creatorcontrib><creatorcontrib>Chen, Kan-Nan</creatorcontrib><creatorcontrib>Wong, David Shan-Hill</creatorcontrib><collection>CrossRef</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>Industrial & engineering chemistry research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yang, Ping-Lin</au><au>Tsai, Sung-Han</au><au>Han, Yao-Yi</au><au>Chao, Hsien-Wen</au><au>Chen, Kan-Nan</au><au>Wong, David Shan-Hill</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ionic Liquid as a Catalyst toward NIPU via a Microwave Radiation Process</atitle><jtitle>Industrial & engineering chemistry research</jtitle><addtitle>Ind. Eng. Chem. Res</addtitle><date>2024-10-08</date><risdate>2024</risdate><volume>63</volume><issue>41</issue><spage>17430</spage><epage>17440</epage><pages>17430-17440</pages><issn>0888-5885</issn><issn>1520-5045</issn><eissn>1520-5045</eissn><abstract>In this work, catalytic and microwave intensification effects on the ring-opening reaction between butanediol bicyclic carbonates and Jeffamine D230 were investigated. It was found that tetrabutyl methyl carbonate has perfect catalytic effects compared to conventional catalysts such as lithium bromide and can be substantially intensified by microwave heating and flow chemistry. The ionic liquid can be easily recovered from the product by using water washing and reused with little decay in reactivity. These results represent significant opportunities for the development of a green and sustainable route of nonisocyanate polyurethane.</abstract><pub>American Chemical Society</pub><doi>10.1021/acs.iecr.4c00510</doi><tpages>11</tpages><orcidid>https://orcid.org/0009-0009-5026-0162</orcidid><orcidid>https://orcid.org/0000-0001-8574-8234</orcidid><oa>free_for_read</oa></addata></record> |
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| identifier | ISSN: 0888-5885 |
| ispartof | Industrial & engineering chemistry research, 2024-10, Vol.63 (41), p.17430-17440 |
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| language | eng |
| recordid | cdi_crossref_primary_10_1021_acs_iecr_4c00510 |
| source | ACS Publications |
| subjects | Applied Chemistry butanediol carbonates catalysts chemistry ionic liquids lithium microwave radiation microwave treatment polyurethanes |
| title | Ionic Liquid as a Catalyst toward NIPU via a Microwave Radiation Process |
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