Determination of the Mass Transfer Parameters and Partition Coefficients for Formic Acid/Water/Soybean Oil System
The formic acid partition coefficients in soybean oil/water biphasic system were determined experimentally in a Lewis cell apparatus and modeled mathematically. The effect of different operation conditions on the mass transfer parameters was investigated, i.e., temperature, water-to-soybean oil weig...
Gespeichert in:
| Veröffentlicht in: | Industrial & engineering chemistry research 2023-09, Vol.62 (35), p.13825-13836 |
|---|---|
| Hauptverfasser: | , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 13836 |
|---|---|
| container_issue | 35 |
| container_start_page | 13825 |
| container_title | Industrial & engineering chemistry research |
| container_volume | 62 |
| creator | Olivieri, Gustavo V. Cogliano, Tommaso Torres, Ricardo Belchior Turco, Rosa Salmi, Tapio Tesser, Riccardo Russo, Vincenzo Di Serio, Martino Giudici, Reinaldo |
| description | The formic acid partition coefficients in soybean oil/water biphasic system were determined experimentally in a Lewis cell apparatus and modeled mathematically. The effect of different operation conditions on the mass transfer parameters was investigated, i.e., temperature, water-to-soybean oil weight ratio, and formic acid-to-soybean + water weight ratio. The experimental results revealed that the temperature and water-to-soybean oil ratio bring the most relevant influence on the partition coefficient. The results were interpreted with an empirical mathematical model and two thermodynamic models, UNIQUAC (Universal Quasichemical) and NRTL (Non-Random Two Liquid). This investigation has relevance for the epoxidation of vegetable oils via the Prilezhaev concept. The approach can also be extended to other carboxylic acids, too. |
| doi_str_mv | 10.1021/acs.iecr.3c01562 |
| format | Article |
| fullrecord | <record><control><sourceid>acs_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1021_acs_iecr_3c01562</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>b060746988</sourcerecordid><originalsourceid>FETCH-LOGICAL-a322t-9fe7b243eeebbb92a5b0403684109abb7b56e85804a1129b03bec8cdcc988a2e3</originalsourceid><addsrcrecordid>eNp1kMFOAjEQhhujiYjePfYBXJh2t9A9EhQ0wWACxuNmWqaxhN1qux54e3eFq6fJZL7_z-Rj7F7ASIAUY7Rp5MnGUW5BqIm8YAOhJGQKCnXJBqC1zpTW6prdpLQHAKWKYsC-H6mlWPsGWx8aHhxvP4m_Ykp8G7FJjiJ_w4h1jyWOza5fW_9HzwM5562npk3chcgXoauyfGb9bvyBXWK8CUdD2PC1P_DNMbVU37Irh4dEd-c5ZO-Lp-38OVutly_z2SrDXMo2Kx1NjSxyIjLGlBKVgQLyiS4ElGjM1KgJaaWhQCFkaSA3ZLXdWVtqjZLyIYNTr40hpUiu-oq-xnisBFS9sqpTVvXKqrOyLvJwivSXffiJTffg__gv3R1x5A</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Determination of the Mass Transfer Parameters and Partition Coefficients for Formic Acid/Water/Soybean Oil System</title><source>ACS Publications</source><creator>Olivieri, Gustavo V. ; Cogliano, Tommaso ; Torres, Ricardo Belchior ; Turco, Rosa ; Salmi, Tapio ; Tesser, Riccardo ; Russo, Vincenzo ; Di Serio, Martino ; Giudici, Reinaldo</creator><creatorcontrib>Olivieri, Gustavo V. ; Cogliano, Tommaso ; Torres, Ricardo Belchior ; Turco, Rosa ; Salmi, Tapio ; Tesser, Riccardo ; Russo, Vincenzo ; Di Serio, Martino ; Giudici, Reinaldo</creatorcontrib><description>The formic acid partition coefficients in soybean oil/water biphasic system were determined experimentally in a Lewis cell apparatus and modeled mathematically. The effect of different operation conditions on the mass transfer parameters was investigated, i.e., temperature, water-to-soybean oil weight ratio, and formic acid-to-soybean + water weight ratio. The experimental results revealed that the temperature and water-to-soybean oil ratio bring the most relevant influence on the partition coefficient. The results were interpreted with an empirical mathematical model and two thermodynamic models, UNIQUAC (Universal Quasichemical) and NRTL (Non-Random Two Liquid). This investigation has relevance for the epoxidation of vegetable oils via the Prilezhaev concept. The approach can also be extended to other carboxylic acids, too.</description><identifier>ISSN: 0888-5885</identifier><identifier>EISSN: 1520-5045</identifier><identifier>DOI: 10.1021/acs.iecr.3c01562</identifier><language>eng</language><publisher>American Chemical Society</publisher><subject>Kinetics, Catalysis, and Reaction Engineering</subject><ispartof>Industrial & engineering chemistry research, 2023-09, Vol.62 (35), p.13825-13836</ispartof><rights>2023 The Authors. Published by American Chemical Society</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a322t-9fe7b243eeebbb92a5b0403684109abb7b56e85804a1129b03bec8cdcc988a2e3</citedby><cites>FETCH-LOGICAL-a322t-9fe7b243eeebbb92a5b0403684109abb7b56e85804a1129b03bec8cdcc988a2e3</cites><orcidid>0000-0001-7002-7194 ; 0000-0002-2681-4286 ; 0000-0001-6544-7098 ; 0000-0002-0791-4775 ; 0000-0001-6225-6157 ; 0000-0003-4489-7115 ; 0000-0001-6373-4181 ; 0000-0002-9271-7425 ; 0000-0002-1867-739X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acs.iecr.3c01562$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acs.iecr.3c01562$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2752,27053,27901,27902,56713,56763</link.rule.ids></links><search><creatorcontrib>Olivieri, Gustavo V.</creatorcontrib><creatorcontrib>Cogliano, Tommaso</creatorcontrib><creatorcontrib>Torres, Ricardo Belchior</creatorcontrib><creatorcontrib>Turco, Rosa</creatorcontrib><creatorcontrib>Salmi, Tapio</creatorcontrib><creatorcontrib>Tesser, Riccardo</creatorcontrib><creatorcontrib>Russo, Vincenzo</creatorcontrib><creatorcontrib>Di Serio, Martino</creatorcontrib><creatorcontrib>Giudici, Reinaldo</creatorcontrib><title>Determination of the Mass Transfer Parameters and Partition Coefficients for Formic Acid/Water/Soybean Oil System</title><title>Industrial & engineering chemistry research</title><addtitle>Ind. Eng. Chem. Res</addtitle><description>The formic acid partition coefficients in soybean oil/water biphasic system were determined experimentally in a Lewis cell apparatus and modeled mathematically. The effect of different operation conditions on the mass transfer parameters was investigated, i.e., temperature, water-to-soybean oil weight ratio, and formic acid-to-soybean + water weight ratio. The experimental results revealed that the temperature and water-to-soybean oil ratio bring the most relevant influence on the partition coefficient. The results were interpreted with an empirical mathematical model and two thermodynamic models, UNIQUAC (Universal Quasichemical) and NRTL (Non-Random Two Liquid). This investigation has relevance for the epoxidation of vegetable oils via the Prilezhaev concept. The approach can also be extended to other carboxylic acids, too.</description><subject>Kinetics, Catalysis, and Reaction Engineering</subject><issn>0888-5885</issn><issn>1520-5045</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1kMFOAjEQhhujiYjePfYBXJh2t9A9EhQ0wWACxuNmWqaxhN1qux54e3eFq6fJZL7_z-Rj7F7ASIAUY7Rp5MnGUW5BqIm8YAOhJGQKCnXJBqC1zpTW6prdpLQHAKWKYsC-H6mlWPsGWx8aHhxvP4m_Ykp8G7FJjiJ_w4h1jyWOza5fW_9HzwM5562npk3chcgXoauyfGb9bvyBXWK8CUdD2PC1P_DNMbVU37Irh4dEd-c5ZO-Lp-38OVutly_z2SrDXMo2Kx1NjSxyIjLGlBKVgQLyiS4ElGjM1KgJaaWhQCFkaSA3ZLXdWVtqjZLyIYNTr40hpUiu-oq-xnisBFS9sqpTVvXKqrOyLvJwivSXffiJTffg__gv3R1x5A</recordid><startdate>20230906</startdate><enddate>20230906</enddate><creator>Olivieri, Gustavo V.</creator><creator>Cogliano, Tommaso</creator><creator>Torres, Ricardo Belchior</creator><creator>Turco, Rosa</creator><creator>Salmi, Tapio</creator><creator>Tesser, Riccardo</creator><creator>Russo, Vincenzo</creator><creator>Di Serio, Martino</creator><creator>Giudici, Reinaldo</creator><general>American Chemical Society</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0001-7002-7194</orcidid><orcidid>https://orcid.org/0000-0002-2681-4286</orcidid><orcidid>https://orcid.org/0000-0001-6544-7098</orcidid><orcidid>https://orcid.org/0000-0002-0791-4775</orcidid><orcidid>https://orcid.org/0000-0001-6225-6157</orcidid><orcidid>https://orcid.org/0000-0003-4489-7115</orcidid><orcidid>https://orcid.org/0000-0001-6373-4181</orcidid><orcidid>https://orcid.org/0000-0002-9271-7425</orcidid><orcidid>https://orcid.org/0000-0002-1867-739X</orcidid></search><sort><creationdate>20230906</creationdate><title>Determination of the Mass Transfer Parameters and Partition Coefficients for Formic Acid/Water/Soybean Oil System</title><author>Olivieri, Gustavo V. ; Cogliano, Tommaso ; Torres, Ricardo Belchior ; Turco, Rosa ; Salmi, Tapio ; Tesser, Riccardo ; Russo, Vincenzo ; Di Serio, Martino ; Giudici, Reinaldo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a322t-9fe7b243eeebbb92a5b0403684109abb7b56e85804a1129b03bec8cdcc988a2e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Kinetics, Catalysis, and Reaction Engineering</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Olivieri, Gustavo V.</creatorcontrib><creatorcontrib>Cogliano, Tommaso</creatorcontrib><creatorcontrib>Torres, Ricardo Belchior</creatorcontrib><creatorcontrib>Turco, Rosa</creatorcontrib><creatorcontrib>Salmi, Tapio</creatorcontrib><creatorcontrib>Tesser, Riccardo</creatorcontrib><creatorcontrib>Russo, Vincenzo</creatorcontrib><creatorcontrib>Di Serio, Martino</creatorcontrib><creatorcontrib>Giudici, Reinaldo</creatorcontrib><collection>CrossRef</collection><jtitle>Industrial & engineering chemistry research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Olivieri, Gustavo V.</au><au>Cogliano, Tommaso</au><au>Torres, Ricardo Belchior</au><au>Turco, Rosa</au><au>Salmi, Tapio</au><au>Tesser, Riccardo</au><au>Russo, Vincenzo</au><au>Di Serio, Martino</au><au>Giudici, Reinaldo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Determination of the Mass Transfer Parameters and Partition Coefficients for Formic Acid/Water/Soybean Oil System</atitle><jtitle>Industrial & engineering chemistry research</jtitle><addtitle>Ind. Eng. Chem. Res</addtitle><date>2023-09-06</date><risdate>2023</risdate><volume>62</volume><issue>35</issue><spage>13825</spage><epage>13836</epage><pages>13825-13836</pages><issn>0888-5885</issn><eissn>1520-5045</eissn><abstract>The formic acid partition coefficients in soybean oil/water biphasic system were determined experimentally in a Lewis cell apparatus and modeled mathematically. The effect of different operation conditions on the mass transfer parameters was investigated, i.e., temperature, water-to-soybean oil weight ratio, and formic acid-to-soybean + water weight ratio. The experimental results revealed that the temperature and water-to-soybean oil ratio bring the most relevant influence on the partition coefficient. The results were interpreted with an empirical mathematical model and two thermodynamic models, UNIQUAC (Universal Quasichemical) and NRTL (Non-Random Two Liquid). This investigation has relevance for the epoxidation of vegetable oils via the Prilezhaev concept. The approach can also be extended to other carboxylic acids, too.</abstract><pub>American Chemical Society</pub><doi>10.1021/acs.iecr.3c01562</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0001-7002-7194</orcidid><orcidid>https://orcid.org/0000-0002-2681-4286</orcidid><orcidid>https://orcid.org/0000-0001-6544-7098</orcidid><orcidid>https://orcid.org/0000-0002-0791-4775</orcidid><orcidid>https://orcid.org/0000-0001-6225-6157</orcidid><orcidid>https://orcid.org/0000-0003-4489-7115</orcidid><orcidid>https://orcid.org/0000-0001-6373-4181</orcidid><orcidid>https://orcid.org/0000-0002-9271-7425</orcidid><orcidid>https://orcid.org/0000-0002-1867-739X</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0888-5885 |
| ispartof | Industrial & engineering chemistry research, 2023-09, Vol.62 (35), p.13825-13836 |
| issn | 0888-5885 1520-5045 |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_acs_iecr_3c01562 |
| source | ACS Publications |
| subjects | Kinetics, Catalysis, and Reaction Engineering |
| title | Determination of the Mass Transfer Parameters and Partition Coefficients for Formic Acid/Water/Soybean Oil System |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-31T00%3A31%3A39IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Determination%20of%20the%20Mass%20Transfer%20Parameters%20and%20Partition%20Coefficients%20for%20Formic%20Acid/Water/Soybean%20Oil%20System&rft.jtitle=Industrial%20&%20engineering%20chemistry%20research&rft.au=Olivieri,%20Gustavo%20V.&rft.date=2023-09-06&rft.volume=62&rft.issue=35&rft.spage=13825&rft.epage=13836&rft.pages=13825-13836&rft.issn=0888-5885&rft.eissn=1520-5045&rft_id=info:doi/10.1021/acs.iecr.3c01562&rft_dat=%3Cacs_cross%3Eb060746988%3C/acs_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |