Minerals to Materials: Bulk Synthesis of Aqueous Aluminum Clusters and Their Use as Precursors for Metal Oxide Thin Films

We describe a process to produce aqueous precursor solutions of the flat -Al 13 hydroxo cluster (Al13(μ3-OH)6(μ2-OH)18(H2O)24(NO3)15) via stoichiometric dissolution of bulk Al­(OH)3(s) in HNO3(aq). We highlight its facility by demonstrating high yields and large-scale synthesis. X-ray diffraction co...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Chemistry of materials 2017-09, Vol.29 (18), p.7760-7765
Hauptverfasser:	Fulton, Brantly L, Perkins, Cory K, Mansergh, Ryan H, Jenkins, Melanie A, Gouliouk, Vasily, Jackson, Milton N, Ramos, Juan C, Rogovoy, Nichole M, Gutierrez-Higgins, Maceo T, Boettcher, Shannon W, Conley, John F, Keszler, Douglas A, Hutchison, James E, Johnson, Darren W
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!