Interfacial Insight from Operando XAS/TEM for Magnesium Metal Deposition with Borohydride Electrolytes

Interfacial Insight from Operando XAS/TEM for Magnesium Metal Deposition with Borohydride Electrolytes

Operando soft X-ray absorption spectroscopy (sXAS) and transmission electron microscopy (TEM) of the electrochemical deposition of magnesium metal from borohydride electrolytes is presented. The analysis identifies the active component for the deposition of magnesium metal as the contact-ion pair [M...

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Veröffentlicht in:Chemistry of materials 2017-09, Vol.29 (17), p.7183-7188
Hauptverfasser: Arthur, Timothy S, Glans, Per-Anders, Singh, Nikhilendra, Tutusaus, Oscar, Nie, Kaiqi, Liu, Yi-Sheng, Mizuno, Fuminori, Guo, Jinghua, Alsem, Daan Hein, Salmon, Norman J, Mohtadi, Rana
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container_end_page 7188
container_issue 17
container_start_page 7183
container_title Chemistry of materials
container_volume 29
creator Arthur, Timothy S
Glans, Per-Anders
Singh, Nikhilendra
Tutusaus, Oscar
Nie, Kaiqi
Liu, Yi-Sheng
Mizuno, Fuminori
Guo, Jinghua
Alsem, Daan Hein
Salmon, Norman J
Mohtadi, Rana
description Operando soft X-ray absorption spectroscopy (sXAS) and transmission electron microscopy (TEM) of the electrochemical deposition of magnesium metal from borohydride electrolytes is presented. The analysis identifies the active component for the deposition of magnesium metal as the contact-ion pair [Mg­(μ-H)2BH2]+. Additionally, the formation of boron clusters accompanied by H2 -gas formation accompany the deposition of Mg metal, and play a vital role in the formation of a solid-electrolyte interphase (SEI) on the surface. To use Mg metal as a viable anode for future battery systems, understanding the interfacial components and chemistry is key.
doi_str_mv 10.1021/acs.chemmater.7b01189
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