Assembly of Cu(I) Alkynyl Complexes: From Cluster to Infinite Cluster-Based Framework
Variation of the reaction conditions with Cu powder, Cu(NO3)2, and t BuCCH as starting materials afforded three new Cu(I) alkynyl complexes, namely, [Cu14( t BuCC)10(NO3)4(MeOH)2]·H2O (1), Cu15( t BuCC)14(NO3) (2), and [Cu14( t BuCC)8(NO3)2(CN)4] n (3). Single-crystal X-ray analysis reve...
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| Veröffentlicht in: | Crystal growth & design 2019-10, Vol.19 (10), p.5791-5797 |
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| container_title | Crystal growth & design |
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| creator | Xie, Yun-Peng Wen, Jun-Bo Pan, Chang-Wang Duan, Guang-Xiong Li, Lan-Yun Lu, Xing |
| description | Variation of the reaction conditions with Cu powder, Cu(NO3)2, and t BuCCH as starting materials afforded three new Cu(I) alkynyl complexes, namely, [Cu14( t BuCC)10(NO3)4(MeOH)2]·H2O (1), Cu15( t BuCC)14(NO3) (2), and [Cu14( t BuCC)8(NO3)2(CN)4] n (3). Single-crystal X-ray analysis revealed that clusters 1 and 2 consist of Cu14 and Cu15 cores costabilized by strong by σ- and π-bonded tert-butylethynides and nitrates. Complex 3 displays an intriguing three-dimensional cyano-bridged Cu(I) alkynyl cluster-based framework, in which the existence of CN– is assumed to have originated from the Cu(I)-mediated C–C cleavage reaction of acetonitrile under mild solvothermal conditions. |
| doi_str_mv | 10.1021/acs.cgd.9b00803 |
| format | Article |
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Single-crystal X-ray analysis revealed that clusters 1 and 2 consist of Cu14 and Cu15 cores costabilized by strong by σ- and π-bonded tert-butylethynides and nitrates. Complex 3 displays an intriguing three-dimensional cyano-bridged Cu(I) alkynyl cluster-based framework, in which the existence of CN– is assumed to have originated from the Cu(I)-mediated C–C cleavage reaction of acetonitrile under mild solvothermal conditions.</description><identifier>ISSN: 1528-7483</identifier><identifier>EISSN: 1528-7505</identifier><identifier>DOI: 10.1021/acs.cgd.9b00803</identifier><language>eng</language><publisher>American Chemical Society</publisher><ispartof>Crystal growth & design, 2019-10, Vol.19 (10), p.5791-5797</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a277t-2ca2a3a9a3367eed84017e4e7b6697d0c208dd136a0667eccecbd426093866a13</citedby><cites>FETCH-LOGICAL-a277t-2ca2a3a9a3367eed84017e4e7b6697d0c208dd136a0667eccecbd426093866a13</cites><orcidid>0000-0003-2741-8733 ; 0000-0002-4065-9809</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acs.cgd.9b00803$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acs.cgd.9b00803$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>315,781,785,2766,27081,27929,27930,56743,56793</link.rule.ids></links><search><creatorcontrib>Xie, Yun-Peng</creatorcontrib><creatorcontrib>Wen, Jun-Bo</creatorcontrib><creatorcontrib>Pan, Chang-Wang</creatorcontrib><creatorcontrib>Duan, Guang-Xiong</creatorcontrib><creatorcontrib>Li, Lan-Yun</creatorcontrib><creatorcontrib>Lu, Xing</creatorcontrib><title>Assembly of Cu(I) Alkynyl Complexes: From Cluster to Infinite Cluster-Based Framework</title><title>Crystal growth & design</title><addtitle>Cryst. Growth Des</addtitle><description>Variation of the reaction conditions with Cu powder, Cu(NO3)2, and t BuCCH as starting materials afforded three new Cu(I) alkynyl complexes, namely, [Cu14( t BuCC)10(NO3)4(MeOH)2]·H2O (1), Cu15( t BuCC)14(NO3) (2), and [Cu14( t BuCC)8(NO3)2(CN)4] n (3). Single-crystal X-ray analysis revealed that clusters 1 and 2 consist of Cu14 and Cu15 cores costabilized by strong by σ- and π-bonded tert-butylethynides and nitrates. Complex 3 displays an intriguing three-dimensional cyano-bridged Cu(I) alkynyl cluster-based framework, in which the existence of CN– is assumed to have originated from the Cu(I)-mediated C–C cleavage reaction of acetonitrile under mild solvothermal conditions.</description><issn>1528-7483</issn><issn>1528-7505</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1kEFPwzAMRiMEEmNw5pojCLVzki5puY2KwaRJXNi5ShMXbWubKekE_ffrtO3IyZb9Pst6hDwyiBlwNtEmxObHxlkJkIK4IiM25WmkpjC9vvRJKm7JXQgbAFBSiBFZzULApqx76iqa758Wz3RWb_u2r2numl2Nfxhe6dy7hub1PnToaefooq3W7brDyyx60wHtgOkGf53f3pObStcBH851TFbz9-_8M1p-fSzy2TLSXKku4kZzLXSmhZAK0aYJMIUJqlLKTFkwHFJrmZAa5AAYg6a0CZeQiVRKzcSYTE53jXcheKyKnV832vcFg-JopRisFIOV4mxlSLycEsfFxu19O_z3L30Aml5k3w</recordid><startdate>20191002</startdate><enddate>20191002</enddate><creator>Xie, Yun-Peng</creator><creator>Wen, Jun-Bo</creator><creator>Pan, Chang-Wang</creator><creator>Duan, Guang-Xiong</creator><creator>Li, Lan-Yun</creator><creator>Lu, Xing</creator><general>American Chemical Society</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-2741-8733</orcidid><orcidid>https://orcid.org/0000-0002-4065-9809</orcidid></search><sort><creationdate>20191002</creationdate><title>Assembly of Cu(I) Alkynyl Complexes: From Cluster to Infinite Cluster-Based Framework</title><author>Xie, Yun-Peng ; Wen, Jun-Bo ; Pan, Chang-Wang ; Duan, Guang-Xiong ; Li, Lan-Yun ; Lu, Xing</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a277t-2ca2a3a9a3367eed84017e4e7b6697d0c208dd136a0667eccecbd426093866a13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xie, Yun-Peng</creatorcontrib><creatorcontrib>Wen, Jun-Bo</creatorcontrib><creatorcontrib>Pan, Chang-Wang</creatorcontrib><creatorcontrib>Duan, Guang-Xiong</creatorcontrib><creatorcontrib>Li, Lan-Yun</creatorcontrib><creatorcontrib>Lu, Xing</creatorcontrib><collection>CrossRef</collection><jtitle>Crystal growth & design</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xie, Yun-Peng</au><au>Wen, Jun-Bo</au><au>Pan, Chang-Wang</au><au>Duan, Guang-Xiong</au><au>Li, Lan-Yun</au><au>Lu, Xing</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Assembly of Cu(I) Alkynyl Complexes: From Cluster to Infinite Cluster-Based Framework</atitle><jtitle>Crystal growth & design</jtitle><addtitle>Cryst. Growth Des</addtitle><date>2019-10-02</date><risdate>2019</risdate><volume>19</volume><issue>10</issue><spage>5791</spage><epage>5797</epage><pages>5791-5797</pages><issn>1528-7483</issn><eissn>1528-7505</eissn><abstract>Variation of the reaction conditions with Cu powder, Cu(NO3)2, and t BuCCH as starting materials afforded three new Cu(I) alkynyl complexes, namely, [Cu14( t BuCC)10(NO3)4(MeOH)2]·H2O (1), Cu15( t BuCC)14(NO3) (2), and [Cu14( t BuCC)8(NO3)2(CN)4] n (3). Single-crystal X-ray analysis revealed that clusters 1 and 2 consist of Cu14 and Cu15 cores costabilized by strong by σ- and π-bonded tert-butylethynides and nitrates. Complex 3 displays an intriguing three-dimensional cyano-bridged Cu(I) alkynyl cluster-based framework, in which the existence of CN– is assumed to have originated from the Cu(I)-mediated C–C cleavage reaction of acetonitrile under mild solvothermal conditions.</abstract><pub>American Chemical Society</pub><doi>10.1021/acs.cgd.9b00803</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0003-2741-8733</orcidid><orcidid>https://orcid.org/0000-0002-4065-9809</orcidid></addata></record> |
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| title | Assembly of Cu(I) Alkynyl Complexes: From Cluster to Infinite Cluster-Based Framework |
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