Spin-Canted Antiferromagnetic Ordering in Transition Metal–Organic Frameworks Based on Tetranuclear Clusters with Mixed V- and Y‑Shaped Ligands

Four transition metal–organic frameworks were solvothermally synthesized with V-shaped 1,3-bis­(1-imidazolyl)­benzene (bib) and two Y-shaped carboxylate ligands (1,3,5-benzenetricarboxylic acid (H3btc) and 3,5-pyridinedicarboxylic acid (H2pydc)), namely, {[M2(μ3-OH)­(bib)­(btc)]­·H2O} n (M = Co (1)...

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Veröffentlicht in:Crystal growth & design 2017-09, Vol.17 (9), p.4757-4765
Hauptverfasser: Cao, Chen, Liu, Sui-Jun, Yao, Shu-Li, Zheng, Teng-Fei, Chen, Yong-Qiang, Chen, Jing-Lin, Wen, He-Rui
Format: Artikel
Sprache:eng
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