Engineering of Organic Chromophores with Large Second-Order Optical Nonlinearity and Superior Crystal Growth Ability

Engineering of Organic Chromophores with Large Second-Order Optical Nonlinearity and Superior Crystal Growth Ability

We present two D-π-A organic cationic core structures leading to highly efficient nonlinear optical (NLO) salts (E)-2-(4-(dimethylamino)­styryl)-1,1,3-trimethyl-1H-benzo­[e]­indol-3-ium iodide (P–BI) and (E)-2-(2-(5-(dimethylamino)­thiophen-2-yl) vinyl)-1,1,3 -trimethyl-1H-benzo­[e]­indol-3-ium iodi...

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Veröffentlicht in:Crystal growth & design 2015-11, Vol.15 (11), p.5560-5567
Hauptverfasser: Chen, Honghong, Ma, Qi, Zhou, Yuqiao, Yang, Zhou, Jazbinsek, Mojca, Bian, Yongzhong, Ye, Ning, Wang, Dong, Cao, Hui, He, Wanli
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container_end_page 5567
container_issue 11
container_start_page 5560
container_title Crystal growth & design
container_volume 15
creator Chen, Honghong
Ma, Qi
Zhou, Yuqiao
Yang, Zhou
Jazbinsek, Mojca
Bian, Yongzhong
Ye, Ning
Wang, Dong
Cao, Hui
He, Wanli
description We present two D-π-A organic cationic core structures leading to highly efficient nonlinear optical (NLO) salts (E)-2-(4-(dimethylamino)­styryl)-1,1,3-trimethyl-1H-benzo­[e]­indol-3-ium iodide (P–BI) and (E)-2-(2-(5-(dimethylamino)­thiophen-2-yl) vinyl)-1,1,3 -trimethyl-1H-benzo­[e]­indol-3-ium iodide (S–BI). Single crystals of the above two materials were successfully obtained by the slow evaporation method. Two different polymorphic crystals of both P–BI and S–BI were obtained from different polar solvents. Kurtz powder tests revealed that the maximum second harmonic generation (SHG) efficiency of P–BI with monoclinic space group P21 is 1.14 times the benchmark DAST­(4-N,N-dimethylamino-4,-N,-methylstilbazolium tosylate). Bulk single crystals of P–BI were obtained with size of up to 17.0 × 6.0 × 2.0 mm3 without using seed crystals. This demonstrates that this material exhibits great crystal growth ability along with a high second-order optical nonlinearity, making it a very attractive candidate for NLO applications such as electro-optics and THz-wave generation.
doi_str_mv 10.1021/acs.cgd.5b01216
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Bulk single crystals of P–BI were obtained with size of up to 17.0 × 6.0 × 2.0 mm3 without using seed crystals. This demonstrates that this material exhibits great crystal growth ability along with a high second-order optical nonlinearity, making it a very attractive candidate for NLO applications such as electro-optics and THz-wave generation.</abstract><pub>American Chemical Society</pub><doi>10.1021/acs.cgd.5b01216</doi><tpages>8</tpages></addata></record>
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