From Two-Dimensional Layers to Three-Dimensional Frameworks: Expanding the Structural Diversity of Uranyl Compounds by Cation–Cation Interactions

Two uranyl tungstates, Cs4[(UO2)4­(WO5)­(W2O8)­O2] (CsUW-1) and Cs4[(UO2)7­(WO5)3O3] (CsUW-2), were obtained via the high-temperature solid-state synthesis method by reacting uranyl nitrate with WO3 in the presence of cesium nitrate. CsUW-1 crystallizes in space group P21 /n, adopting a two-dimensio...

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Veröffentlicht in:Crystal growth & design 2015-08, Vol.15 (8), p.3775-3784
Hauptverfasser: Xiao, Bin, Schlenz, Hartmut, Dellen, Jakob, Bosbach, Dirk, Suleimanov, Evgeny V, Alekseev, Evgeny V
Format: Artikel
Sprache:eng
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