Rare Fluorescence Red-Shifted Metal–Organic Framework Sensor for Methylamine Derived from an N‑Donor Ligand
A three-dimensional (3D) metal–organic framework (MOF) [Cd(bbip)(NDC)] n (JXUST-8, bbip = 2,6-bis(benzimidazol-1-yl)pyridine, and H2NDC = 2,6-naphthalenedicarboxylic acid) with 8-connected bcg topology has been solvothermally synthesized and fully characterized. The fluorescence experiments demo...
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| Veröffentlicht in: | Crystal growth & design 2021-10, Vol.21 (10), p.5765-5772 |
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| container_title | Crystal growth & design |
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| creator | Yao, Shu-Li Xu, Hui Zheng, Teng-Fei Liu, Sui-Jun Chen, Jing-Lin Wen, He-Rui |
| description | A three-dimensional (3D) metal–organic framework (MOF) [Cd(bbip)(NDC)] n (JXUST-8, bbip = 2,6-bis(benzimidazol-1-yl)pyridine, and H2NDC = 2,6-naphthalenedicarboxylic acid) with 8-connected bcg topology has been solvothermally synthesized and fully characterized. The fluorescence experiments demonstrate that JXUST-8 could selectively distinguish methylamine (MA) by fluorescence red shift, and the detection limit is 0.341 ppm. It is noteworthy that red-shift emission could enlarge the fluorescence signal, which is beneficial to realize sensing. In addition, JXUST-8 performs relatively good thermal stability, chemical stability, and reusability. Importantly, JXUST-8 could be considered as the first example of a bbip-based MOF as well as the second case of a fluorescence red-shifted MOF sensor toward MA. |
| doi_str_mv | 10.1021/acs.cgd.1c00672 |
| format | Article |
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The fluorescence experiments demonstrate that JXUST-8 could selectively distinguish methylamine (MA) by fluorescence red shift, and the detection limit is 0.341 ppm. It is noteworthy that red-shift emission could enlarge the fluorescence signal, which is beneficial to realize sensing. In addition, JXUST-8 performs relatively good thermal stability, chemical stability, and reusability. 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Growth Des</addtitle><date>2021-10-06</date><risdate>2021</risdate><volume>21</volume><issue>10</issue><spage>5765</spage><epage>5772</epage><pages>5765-5772</pages><issn>1528-7483</issn><eissn>1528-7505</eissn><abstract>A three-dimensional (3D) metal–organic framework (MOF) [Cd(bbip)(NDC)] n (JXUST-8, bbip = 2,6-bis(benzimidazol-1-yl)pyridine, and H2NDC = 2,6-naphthalenedicarboxylic acid) with 8-connected bcg topology has been solvothermally synthesized and fully characterized. The fluorescence experiments demonstrate that JXUST-8 could selectively distinguish methylamine (MA) by fluorescence red shift, and the detection limit is 0.341 ppm. It is noteworthy that red-shift emission could enlarge the fluorescence signal, which is beneficial to realize sensing. In addition, JXUST-8 performs relatively good thermal stability, chemical stability, and reusability. Importantly, JXUST-8 could be considered as the first example of a bbip-based MOF as well as the second case of a fluorescence red-shifted MOF sensor toward MA.</abstract><pub>American Chemical Society</pub><doi>10.1021/acs.cgd.1c00672</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-7705-0634</orcidid><orcidid>https://orcid.org/0000-0002-1973-9273</orcidid><orcidid>https://orcid.org/0000-0002-6457-0729</orcidid><orcidid>https://orcid.org/0000-0002-6497-2955</orcidid></addata></record> |
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| source | ACS Publications |
| title | Rare Fluorescence Red-Shifted Metal–Organic Framework Sensor for Methylamine Derived from an N‑Donor Ligand |
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