Analysis of chloride-doped cadmium sulfide by ion chromatography
Cadmium sulfide doped with cadmium chloride can be used as a superconductor at noncryogenic temperatures. The level of chloride and its manner of incorporation (either within the crystal lattice or merely as an intimate mixture) may be critical parameters to the effectiveness of the compound as a su...
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| Veröffentlicht in: | Anal. Chem.; (United States) 1982-02, Vol.54 (2), p.340-342 |
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| container_title | Anal. Chem.; (United States) |
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| creator | Koch, William F Stolz, Jeffrey W |
| description | Cadmium sulfide doped with cadmium chloride can be used as a superconductor at noncryogenic temperatures. The level of chloride and its manner of incorporation (either within the crystal lattice or merely as an intimate mixture) may be critical parameters to the effectiveness of the compound as a superconductor. Procedures for the rapid determination of chloride were described. It was demonstrated that cadmium sulfide could be dissolved in alkaline hydrogen peroxide and subsequently analyzed for total chlorine and sulfur content by ion chromatography. Possibly total bromine and the other halogens can be similarly characterized in halogen-doped cadmium sulfide. The soluble anionic components of cadmium sulfide can be profiled by ion chromatography after extraction by sonication. 4 tables. (DP) |
| doi_str_mv | 10.1021/ac00239a050 |
| format | Article |
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The level of chloride and its manner of incorporation (either within the crystal lattice or merely as an intimate mixture) may be critical parameters to the effectiveness of the compound as a superconductor. Procedures for the rapid determination of chloride were described. It was demonstrated that cadmium sulfide could be dissolved in alkaline hydrogen peroxide and subsequently analyzed for total chlorine and sulfur content by ion chromatography. Possibly total bromine and the other halogens can be similarly characterized in halogen-doped cadmium sulfide. The soluble anionic components of cadmium sulfide can be profiled by ion chromatography after extraction by sonication. 4 tables. 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Chem.; (United States)</title><addtitle>Anal. Chem</addtitle><description>Cadmium sulfide doped with cadmium chloride can be used as a superconductor at noncryogenic temperatures. The level of chloride and its manner of incorporation (either within the crystal lattice or merely as an intimate mixture) may be critical parameters to the effectiveness of the compound as a superconductor. Procedures for the rapid determination of chloride were described. It was demonstrated that cadmium sulfide could be dissolved in alkaline hydrogen peroxide and subsequently analyzed for total chlorine and sulfur content by ion chromatography. Possibly total bromine and the other halogens can be similarly characterized in halogen-doped cadmium sulfide. The soluble anionic components of cadmium sulfide can be profiled by ion chromatography after extraction by sonication. 4 tables. 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Procedures for the rapid determination of chloride were described. It was demonstrated that cadmium sulfide could be dissolved in alkaline hydrogen peroxide and subsequently analyzed for total chlorine and sulfur content by ion chromatography. Possibly total bromine and the other halogens can be similarly characterized in halogen-doped cadmium sulfide. The soluble anionic components of cadmium sulfide can be profiled by ion chromatography after extraction by sonication. 4 tables. (DP)</abstract><cop>United States</cop><pub>American Chemical Society</pub><doi>10.1021/ac00239a050</doi><tpages>3</tpages></addata></record> |
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| ispartof | Anal. Chem.; (United States), 1982-02, Vol.54 (2), p.340-342 |
| issn | 0003-2700 1520-6882 |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_ac00239a050 |
| source | ACS Publications |
| subjects | 400102 - Chemical & Spectral Procedures 420201 - Engineering- Cryogenic Equipment & Devices CADMIUM CHLORIDES CADMIUM COMPOUNDS CADMIUM HALIDES CADMIUM SULFIDES CHALCOGENIDES CHLORIDES CHLORINE COMPOUNDS CHROMATOGRAPHY CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS DOPED MATERIALS ELEMENTS HALIDES HALOGEN COMPOUNDS INORGANIC PHOSPHORS INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ION EXCHANGE CHROMATOGRAPHY MATERIALS NONMETALS PHOSPHORS SEPARATION PROCESSES SULFIDES SULFUR SULFUR COMPOUNDS SUPERCONDUCTORS |
| title | Analysis of chloride-doped cadmium sulfide by ion chromatography |
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