Methanol-water association and its effect on solute retention in liquid chromatography

Previous work on the association of methanol with water in methanol-water mixtures has been extended. With the use of published data on the volume change on mixing, density, and refractive index, the mean value for the association constant for methanol and water is found to be 5.22 /times/ 10/sup -3...

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Veröffentlicht in:	Anal. Chem.; (United States) 1989-02, Vol.61 (4), p.349-355
Hauptverfasser:	Katz, E. D, Lochmuller, C. H, Scott, R. P. W
Format:	Artikel
Sprache:	eng
Schlagworte:	400201 - Chemical & Physicochemical Properties ALCOHOLS Analytical chemistry AQUEOUS SOLUTIONS BINARY MIXTURES Chemistry Chromatographic methods and physical methods associated with chromatography CHROMATOGRAPHY DATA DENSITY DISPERSIONS EQUATIONS Exact sciences and technology EXPERIMENTAL DATA HYDROGEN COMPOUNDS HYDROXY COMPOUNDS INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY LIQUID COLUMN CHROMATOGRAPHY METHANOL MIXTURES NUMERICAL DATA OPTICAL PROPERTIES ORGANIC COMPOUNDS Other chromatographic methods OXYGEN COMPOUNDS PHASE STUDIES PHYSICAL PROPERTIES PREDICTION EQUATIONS QUANTITY RATIO REFRACTIVITY SEPARATION PROCESSES SOLUTES SOLUTIONS SOLVENTS VOLUME WATER
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