Generation of chemiluminescence upon reaction of aliphatic amines with tris(2,2'-bipyridine)ruthenium(III)
Tris(2,2'-bipyridine)ruthenium(III) (Ru(bpy)/sub 3//sup 3 +/) will undergo an electron-transfer reaction with an appropriate reducing agent to form Ru(bpy)/sub 3//sup 2 +/, which upon achieving an excited state can result in chemiluminescence. Aliphatic amines with an increasing number of carbo...
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| Veröffentlicht in: | Anal. Chem.; (United States) 1987-03, Vol.59 (6), p.865-868 |
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| container_title | Anal. Chem.; (United States) |
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| creator | Noffsinger, James B Danielson, Neil D |
| description | Tris(2,2'-bipyridine)ruthenium(III) (Ru(bpy)/sub 3//sup 3 +/) will undergo an electron-transfer reaction with an appropriate reducing agent to form Ru(bpy)/sub 3//sup 2 +/, which upon achieving an excited state can result in chemiluminescence. Aliphatic amines with an increasing number of carbon atoms were tested between a pH of 4 and 6 and found to act as chemiluminescent reducing agents. In addition, some diamines and phosphines were also found to react. Linear range and detection limit studies were done for the mono-, di-, and tri-n-propylamines as well as other selected compounds. Linear range values for these amines varied between approximately 3 and 5 orders of magnitude. The lowest detection limit of 0.28 pmol was found for tri-n-propylamine. Ionization potentials taken from photoelectron spectroscopy data for aliphatic amines were related linearly with the log of the chemiluminescent signal intensity. In addition, it appeared that assignment of the first ionization potential from a nonbonding orbital of the heteroatom was required for chemiluminscence. |
| doi_str_mv | 10.1021/ac00133a017 |
| format | Article |
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Aliphatic amines with an increasing number of carbon atoms were tested between a pH of 4 and 6 and found to act as chemiluminescent reducing agents. In addition, some diamines and phosphines were also found to react. Linear range and detection limit studies were done for the mono-, di-, and tri-n-propylamines as well as other selected compounds. Linear range values for these amines varied between approximately 3 and 5 orders of magnitude. The lowest detection limit of 0.28 pmol was found for tri-n-propylamine. Ionization potentials taken from photoelectron spectroscopy data for aliphatic amines were related linearly with the log of the chemiluminescent signal intensity. In addition, it appeared that assignment of the first ionization potential from a nonbonding orbital of the heteroatom was required for chemiluminscence.</description><identifier>ISSN: 0003-2700</identifier><identifier>EISSN: 1520-6882</identifier><identifier>DOI: 10.1021/ac00133a017</identifier><identifier>CODEN: ANCHAM</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>AMINES ; Analytical chemistry ; AZINES ; BIPYRIDINES ; CHEMICAL REACTIONS ; CHEMILUMINESCENCE ; Chemistry ; COMPLEXES ; DATA ; ELECTRON SPECTROSCOPY ; ELECTRON TRANSFER ; ENERGY LEVELS ; Exact sciences and technology ; EXCITED STATES ; EXPERIMENTAL DATA ; HETEROCYCLIC COMPOUNDS ; INFORMATION ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; IONIZATION POTENTIAL ; LUMINESCENCE ; NUMERICAL DATA ; ORGANIC COMPOUNDS ; ORGANIC NITROGEN COMPOUNDS ; PH VALUE ; PHOSPHINES ; PHOSPHORUS COMPOUNDS ; PHOTOELECTRON SPECTROSCOPY ; PYRIDINES ; RUTHENIUM COMPLEXES ; Spectrometric and optical methods ; SPECTROSCOPY ; TRANSITION ELEMENT COMPLEXES 400500 -- Photochemistry</subject><ispartof>Anal. Chem.; (United States), 1987-03, Vol.59 (6), p.865-868</ispartof><rights>1987 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a357t-8e9d14009f5ed40da4a17565da97aaa478d8c2d567ff206adfaae91f85683e5a3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ac00133a017$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ac00133a017$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,777,781,882,2752,27057,27905,27906,56719,56769</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=8194829$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/6876593$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Noffsinger, James B</creatorcontrib><creatorcontrib>Danielson, Neil D</creatorcontrib><creatorcontrib>Miami Univ., Oxford, OH</creatorcontrib><title>Generation of chemiluminescence upon reaction of aliphatic amines with tris(2,2'-bipyridine)ruthenium(III)</title><title>Anal. Chem.; (United States)</title><addtitle>Anal. Chem</addtitle><description>Tris(2,2'-bipyridine)ruthenium(III) (Ru(bpy)/sub 3//sup 3 +/) will undergo an electron-transfer reaction with an appropriate reducing agent to form Ru(bpy)/sub 3//sup 2 +/, which upon achieving an excited state can result in chemiluminescence. Aliphatic amines with an increasing number of carbon atoms were tested between a pH of 4 and 6 and found to act as chemiluminescent reducing agents. In addition, some diamines and phosphines were also found to react. Linear range and detection limit studies were done for the mono-, di-, and tri-n-propylamines as well as other selected compounds. Linear range values for these amines varied between approximately 3 and 5 orders of magnitude. The lowest detection limit of 0.28 pmol was found for tri-n-propylamine. Ionization potentials taken from photoelectron spectroscopy data for aliphatic amines were related linearly with the log of the chemiluminescent signal intensity. In addition, it appeared that assignment of the first ionization potential from a nonbonding orbital of the heteroatom was required for chemiluminscence.</description><subject>AMINES</subject><subject>Analytical chemistry</subject><subject>AZINES</subject><subject>BIPYRIDINES</subject><subject>CHEMICAL REACTIONS</subject><subject>CHEMILUMINESCENCE</subject><subject>Chemistry</subject><subject>COMPLEXES</subject><subject>DATA</subject><subject>ELECTRON SPECTROSCOPY</subject><subject>ELECTRON TRANSFER</subject><subject>ENERGY LEVELS</subject><subject>Exact sciences and technology</subject><subject>EXCITED STATES</subject><subject>EXPERIMENTAL DATA</subject><subject>HETEROCYCLIC COMPOUNDS</subject><subject>INFORMATION</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>IONIZATION POTENTIAL</subject><subject>LUMINESCENCE</subject><subject>NUMERICAL DATA</subject><subject>ORGANIC COMPOUNDS</subject><subject>ORGANIC NITROGEN COMPOUNDS</subject><subject>PH VALUE</subject><subject>PHOSPHINES</subject><subject>PHOSPHORUS COMPOUNDS</subject><subject>PHOTOELECTRON SPECTROSCOPY</subject><subject>PYRIDINES</subject><subject>RUTHENIUM COMPLEXES</subject><subject>Spectrometric and optical methods</subject><subject>SPECTROSCOPY</subject><subject>TRANSITION ELEMENT COMPLEXES 400500 -- Photochemistry</subject><issn>0003-2700</issn><issn>1520-6882</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1987</creationdate><recordtype>article</recordtype><recordid>eNpt0F1rFTEQBuAgFjy2XvkHFhHa0q5OspuPvSwH2x4oWGitl2HMJmyO52SXJIv23xtdLb3wai7eZ4bhJeQthQ8UGP2IBoA2DQKVL8iKcga1UIq9JCsAaGomAV6R1yltC6NAxYpsr2ywEbMfQzW6ygx273fz3gebjA3GVvNUkmjR_CO489NQFkyFf1j1w-ehytGnE3bOjutvfnqMvi_RaZzzYIOf9yebzeb0iBw43CX75u88JF8uP92vr-ubz1eb9cVNjQ2XuVa262kL0Dlu-xZ6bJFKLniPnUTEVqpeGdZzIZ1jILB3iLajTnGhGsuxOSTvlrtjyl4n47M1gxlDsCZroaTgXVPQ2YJMHFOK1ukp-j3GR01B_-5SP-uy6PeLnjAZ3LmIwfj0tKJo1yrWFVYvzKdsfz7FGL9rIRvJ9f3tnW6_PqzvLm8fNBR_vHg0SW_HOYbSy38f-AWv5I-w</recordid><startdate>19870315</startdate><enddate>19870315</enddate><creator>Noffsinger, James B</creator><creator>Danielson, Neil D</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19870315</creationdate><title>Generation of chemiluminescence upon reaction of aliphatic amines with tris(2,2'-bipyridine)ruthenium(III)</title><author>Noffsinger, James B ; Danielson, Neil D</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a357t-8e9d14009f5ed40da4a17565da97aaa478d8c2d567ff206adfaae91f85683e5a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1987</creationdate><topic>AMINES</topic><topic>Analytical chemistry</topic><topic>AZINES</topic><topic>BIPYRIDINES</topic><topic>CHEMICAL REACTIONS</topic><topic>CHEMILUMINESCENCE</topic><topic>Chemistry</topic><topic>COMPLEXES</topic><topic>DATA</topic><topic>ELECTRON SPECTROSCOPY</topic><topic>ELECTRON TRANSFER</topic><topic>ENERGY LEVELS</topic><topic>Exact sciences and technology</topic><topic>EXCITED STATES</topic><topic>EXPERIMENTAL DATA</topic><topic>HETEROCYCLIC COMPOUNDS</topic><topic>INFORMATION</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>IONIZATION POTENTIAL</topic><topic>LUMINESCENCE</topic><topic>NUMERICAL DATA</topic><topic>ORGANIC COMPOUNDS</topic><topic>ORGANIC NITROGEN COMPOUNDS</topic><topic>PH VALUE</topic><topic>PHOSPHINES</topic><topic>PHOSPHORUS COMPOUNDS</topic><topic>PHOTOELECTRON SPECTROSCOPY</topic><topic>PYRIDINES</topic><topic>RUTHENIUM COMPLEXES</topic><topic>Spectrometric and optical methods</topic><topic>SPECTROSCOPY</topic><topic>TRANSITION ELEMENT COMPLEXES 400500 -- Photochemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Noffsinger, James B</creatorcontrib><creatorcontrib>Danielson, Neil D</creatorcontrib><creatorcontrib>Miami Univ., Oxford, OH</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Anal. Chem.; (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Noffsinger, James B</au><au>Danielson, Neil D</au><aucorp>Miami Univ., Oxford, OH</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Generation of chemiluminescence upon reaction of aliphatic amines with tris(2,2'-bipyridine)ruthenium(III)</atitle><jtitle>Anal. Chem.; (United States)</jtitle><addtitle>Anal. Chem</addtitle><date>1987-03-15</date><risdate>1987</risdate><volume>59</volume><issue>6</issue><spage>865</spage><epage>868</epage><pages>865-868</pages><issn>0003-2700</issn><eissn>1520-6882</eissn><coden>ANCHAM</coden><abstract>Tris(2,2'-bipyridine)ruthenium(III) (Ru(bpy)/sub 3//sup 3 +/) will undergo an electron-transfer reaction with an appropriate reducing agent to form Ru(bpy)/sub 3//sup 2 +/, which upon achieving an excited state can result in chemiluminescence. Aliphatic amines with an increasing number of carbon atoms were tested between a pH of 4 and 6 and found to act as chemiluminescent reducing agents. In addition, some diamines and phosphines were also found to react. Linear range and detection limit studies were done for the mono-, di-, and tri-n-propylamines as well as other selected compounds. Linear range values for these amines varied between approximately 3 and 5 orders of magnitude. The lowest detection limit of 0.28 pmol was found for tri-n-propylamine. Ionization potentials taken from photoelectron spectroscopy data for aliphatic amines were related linearly with the log of the chemiluminescent signal intensity. In addition, it appeared that assignment of the first ionization potential from a nonbonding orbital of the heteroatom was required for chemiluminscence.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/ac00133a017</doi><tpages>4</tpages></addata></record> |
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| source | ACS Publications |
| subjects | AMINES Analytical chemistry AZINES BIPYRIDINES CHEMICAL REACTIONS CHEMILUMINESCENCE Chemistry COMPLEXES DATA ELECTRON SPECTROSCOPY ELECTRON TRANSFER ENERGY LEVELS Exact sciences and technology EXCITED STATES EXPERIMENTAL DATA HETEROCYCLIC COMPOUNDS INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY IONIZATION POTENTIAL LUMINESCENCE NUMERICAL DATA ORGANIC COMPOUNDS ORGANIC NITROGEN COMPOUNDS PH VALUE PHOSPHINES PHOSPHORUS COMPOUNDS PHOTOELECTRON SPECTROSCOPY PYRIDINES RUTHENIUM COMPLEXES Spectrometric and optical methods SPECTROSCOPY TRANSITION ELEMENT COMPLEXES 400500 -- Photochemistry |
| title | Generation of chemiluminescence upon reaction of aliphatic amines with tris(2,2'-bipyridine)ruthenium(III) |
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