Determination of cobalt, copper, mercury, and nickel as bis(2-hydroxyethyl)dithiocarbamate complexes by high-performance liquid chromatography
Ammonium bis(2-hydroxyethyl)dithiocarbamate (HEDC) is used as a precolumn derivatizing reagent for the reversed-phase HPLC determination of Co(II), Cu(II), Hg(II), and Ni(II). The metal-HEDC complexes are soluble in water, which eliminates the need to extract them into an organic solvent prior to an...
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| Veröffentlicht in: | Anal. Chem.; (United States) 1987-03, Vol.59 (5), p.703-708 |
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| creator | King, Jeffrey N Fritz, James S |
| description | Ammonium bis(2-hydroxyethyl)dithiocarbamate (HEDC) is used as a precolumn derivatizing reagent for the reversed-phase HPLC determination of Co(II), Cu(II), Hg(II), and Ni(II). The metal-HEDC complexes are soluble in water, which eliminates the need to extract them into an organic solvent prior to analysis. Co(II), Cu(II), and Ni(II) can be determined by direct aqueous injection onto a C18 column in the range of 0.005-10.0 mg/L, with a precision of 1.5-3.2%. Detection is at 405 nm. The Hg(II)-HEDC complex is preconcentrated on an on-line adsorption column prior to HPLC analysis. After preconcentration, Hg(II) can be determined in the range of 0.02-25..mu..g/L with a precision of less than 2%. The analysis of spiked electroplating waste waters showed good agreement with expected values. |
| doi_str_mv | 10.1021/ac00132a005 |
| format | Article |
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The metal-HEDC complexes are soluble in water, which eliminates the need to extract them into an organic solvent prior to analysis. Co(II), Cu(II), and Ni(II) can be determined by direct aqueous injection onto a C18 column in the range of 0.005-10.0 mg/L, with a precision of 1.5-3.2%. Detection is at 405 nm. The Hg(II)-HEDC complex is preconcentrated on an on-line adsorption column prior to HPLC analysis. After preconcentration, Hg(II) can be determined in the range of 0.02-25..mu..g/L with a precision of less than 2%. The analysis of spiked electroplating waste waters showed good agreement with expected values.</description><identifier>ISSN: 0003-2700</identifier><identifier>EISSN: 1520-6882</identifier><identifier>DOI: 10.1021/ac00132a005</identifier><identifier>CODEN: ANCHAM</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>520200 -- Environment, Aquatic-- Chemicals Monitoring & Transport-- (-1989) ; AMMONIUM COMPLEXES ; Analytical chemistry ; CARBAMATES ; CARBONIC ACID DERIVATIVES ; CARBOXYLIC ACID SALTS ; CHEMICAL ANALYSIS ; CHEMICAL REACTIONS ; Chemistry ; Chromatographic methods and physical methods associated with chromatography ; CHROMATOGRAPHY ; COBALT ; COBALT COMPLEXES ; COMPLEXES ; COPPER ; COPPER COMPLEXES ; DATA ; DERIVATIZATION ; DITHIOLS ; ELEMENTS ; ENVIRONMENTAL SCIENCES ; Exact sciences and technology ; EXPERIMENTAL DATA ; HYDROGEN COMPOUNDS ; INFORMATION ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; LIQUID COLUMN CHROMATOGRAPHY ; LIQUID WASTES ; MERCURY ; MERCURY COMPLEXES ; METALS ; NICKEL ; NICKEL COMPLEXES ; NUMERICAL DATA ; ORGANIC COMPOUNDS ; ORGANIC NITROGEN COMPOUNDS ; ORGANIC SULFUR COMPOUNDS ; Other chromatographic methods ; OXYGEN COMPOUNDS ; QUANTITATIVE CHEMICAL ANALYSIS ; REAGENTS ; SEPARATION PROCESSES ; SOLUBILITY ; SOLVENT PROPERTIES ; THIOLS ; TRACE AMOUNTS ; TRANSITION ELEMENT COMPLEXES ; TRANSITION ELEMENTS ; WASTE WATER ; WASTES 400102 -- Chemical & Spectral Procedures ; WATER</subject><ispartof>Anal. Chem.; (United States), 1987-03, Vol.59 (5), p.703-708</ispartof><rights>1987 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a482t-b02627358ae5c31644068d3cd7b6c6cb268706e50e0974f39eb0196f563628ff3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ac00132a005$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ac00132a005$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,885,2765,27076,27924,27925,56738,56788</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=8191054$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/6881688$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>King, Jeffrey N</creatorcontrib><creatorcontrib>Fritz, James S</creatorcontrib><creatorcontrib>Iowa State Univ., Ames</creatorcontrib><title>Determination of cobalt, copper, mercury, and nickel as bis(2-hydroxyethyl)dithiocarbamate complexes by high-performance liquid chromatography</title><title>Anal. Chem.; (United States)</title><addtitle>Anal. Chem</addtitle><description>Ammonium bis(2-hydroxyethyl)dithiocarbamate (HEDC) is used as a precolumn derivatizing reagent for the reversed-phase HPLC determination of Co(II), Cu(II), Hg(II), and Ni(II). The metal-HEDC complexes are soluble in water, which eliminates the need to extract them into an organic solvent prior to analysis. Co(II), Cu(II), and Ni(II) can be determined by direct aqueous injection onto a C18 column in the range of 0.005-10.0 mg/L, with a precision of 1.5-3.2%. Detection is at 405 nm. The Hg(II)-HEDC complex is preconcentrated on an on-line adsorption column prior to HPLC analysis. After preconcentration, Hg(II) can be determined in the range of 0.02-25..mu..g/L with a precision of less than 2%. The analysis of spiked electroplating waste waters showed good agreement with expected values.</description><subject>520200 -- Environment, Aquatic-- Chemicals Monitoring & Transport-- (-1989)</subject><subject>AMMONIUM COMPLEXES</subject><subject>Analytical chemistry</subject><subject>CARBAMATES</subject><subject>CARBONIC ACID DERIVATIVES</subject><subject>CARBOXYLIC ACID SALTS</subject><subject>CHEMICAL ANALYSIS</subject><subject>CHEMICAL REACTIONS</subject><subject>Chemistry</subject><subject>Chromatographic methods and physical methods associated with chromatography</subject><subject>CHROMATOGRAPHY</subject><subject>COBALT</subject><subject>COBALT COMPLEXES</subject><subject>COMPLEXES</subject><subject>COPPER</subject><subject>COPPER COMPLEXES</subject><subject>DATA</subject><subject>DERIVATIZATION</subject><subject>DITHIOLS</subject><subject>ELEMENTS</subject><subject>ENVIRONMENTAL SCIENCES</subject><subject>Exact sciences and technology</subject><subject>EXPERIMENTAL DATA</subject><subject>HYDROGEN COMPOUNDS</subject><subject>INFORMATION</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>LIQUID COLUMN CHROMATOGRAPHY</subject><subject>LIQUID WASTES</subject><subject>MERCURY</subject><subject>MERCURY COMPLEXES</subject><subject>METALS</subject><subject>NICKEL</subject><subject>NICKEL COMPLEXES</subject><subject>NUMERICAL DATA</subject><subject>ORGANIC COMPOUNDS</subject><subject>ORGANIC NITROGEN COMPOUNDS</subject><subject>ORGANIC SULFUR COMPOUNDS</subject><subject>Other chromatographic methods</subject><subject>OXYGEN COMPOUNDS</subject><subject>QUANTITATIVE CHEMICAL ANALYSIS</subject><subject>REAGENTS</subject><subject>SEPARATION PROCESSES</subject><subject>SOLUBILITY</subject><subject>SOLVENT PROPERTIES</subject><subject>THIOLS</subject><subject>TRACE AMOUNTS</subject><subject>TRANSITION ELEMENT COMPLEXES</subject><subject>TRANSITION ELEMENTS</subject><subject>WASTE WATER</subject><subject>WASTES 400102 -- Chemical & Spectral Procedures</subject><subject>WATER</subject><issn>0003-2700</issn><issn>1520-6882</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1987</creationdate><recordtype>article</recordtype><recordid>eNpt0M-K1TAUBvAiCl5HV75AEEEHb_UkadPepc74lwsKjoO7cJqeTjPTNjXJhduX8JnNUBlcuAhnkV8-cr4se8rhNQfB36AB4FIgQHkv2_BSQK7qWtzPNgAgc1EBPMwehXCdGAeuNtnvc4rkRzthtG5irmPGNTjEbZrzTH7LRvLm4Jctw6llkzU3NDAMrLHhpcj7pfXuuFDsl-G0tbG3zqBvcMRIKWGcBzpSwgvr7VWfp8DO-REnQ2ywvw62Zab3Lml35XHul8fZgw6HQE_-zpPsx4f3F2ef8v3Xj5_P3u5zLGoR8waEEpUsa6TSSK6KAlTdStNWjTLKNELVFSgqgWBXFZ3cUQN8p7pSSSXqrpMn2bM114VodTA2kumNmyYyUafKeDoJvVqR8S4ET52evR3RL5qDvu1b_9N30s9XPWMwOHQ-bWnD3ZOa7ziURWL5ymyIdLy7Rn-jVSWrUl98-64v918uf76Tlb71L1aPJuhrd_BT6uW_H_gDUM2crw</recordid><startdate>19870301</startdate><enddate>19870301</enddate><creator>King, Jeffrey N</creator><creator>Fritz, James S</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19870301</creationdate><title>Determination of cobalt, copper, mercury, and nickel as bis(2-hydroxyethyl)dithiocarbamate complexes by high-performance liquid chromatography</title><author>King, Jeffrey N ; Fritz, James S</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a482t-b02627358ae5c31644068d3cd7b6c6cb268706e50e0974f39eb0196f563628ff3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1987</creationdate><topic>520200 -- Environment, Aquatic-- Chemicals Monitoring & Transport-- (-1989)</topic><topic>AMMONIUM COMPLEXES</topic><topic>Analytical chemistry</topic><topic>CARBAMATES</topic><topic>CARBONIC ACID DERIVATIVES</topic><topic>CARBOXYLIC ACID SALTS</topic><topic>CHEMICAL ANALYSIS</topic><topic>CHEMICAL REACTIONS</topic><topic>Chemistry</topic><topic>Chromatographic methods and physical methods associated with chromatography</topic><topic>CHROMATOGRAPHY</topic><topic>COBALT</topic><topic>COBALT COMPLEXES</topic><topic>COMPLEXES</topic><topic>COPPER</topic><topic>COPPER COMPLEXES</topic><topic>DATA</topic><topic>DERIVATIZATION</topic><topic>DITHIOLS</topic><topic>ELEMENTS</topic><topic>ENVIRONMENTAL SCIENCES</topic><topic>Exact sciences and technology</topic><topic>EXPERIMENTAL DATA</topic><topic>HYDROGEN COMPOUNDS</topic><topic>INFORMATION</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>LIQUID COLUMN CHROMATOGRAPHY</topic><topic>LIQUID WASTES</topic><topic>MERCURY</topic><topic>MERCURY COMPLEXES</topic><topic>METALS</topic><topic>NICKEL</topic><topic>NICKEL COMPLEXES</topic><topic>NUMERICAL DATA</topic><topic>ORGANIC COMPOUNDS</topic><topic>ORGANIC NITROGEN COMPOUNDS</topic><topic>ORGANIC SULFUR COMPOUNDS</topic><topic>Other chromatographic methods</topic><topic>OXYGEN COMPOUNDS</topic><topic>QUANTITATIVE CHEMICAL ANALYSIS</topic><topic>REAGENTS</topic><topic>SEPARATION PROCESSES</topic><topic>SOLUBILITY</topic><topic>SOLVENT PROPERTIES</topic><topic>THIOLS</topic><topic>TRACE AMOUNTS</topic><topic>TRANSITION ELEMENT COMPLEXES</topic><topic>TRANSITION ELEMENTS</topic><topic>WASTE WATER</topic><topic>WASTES 400102 -- Chemical & Spectral Procedures</topic><topic>WATER</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>King, Jeffrey N</creatorcontrib><creatorcontrib>Fritz, James S</creatorcontrib><creatorcontrib>Iowa State Univ., Ames</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Anal. Chem.; (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>King, Jeffrey N</au><au>Fritz, James S</au><aucorp>Iowa State Univ., Ames</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Determination of cobalt, copper, mercury, and nickel as bis(2-hydroxyethyl)dithiocarbamate complexes by high-performance liquid chromatography</atitle><jtitle>Anal. Chem.; (United States)</jtitle><addtitle>Anal. Chem</addtitle><date>1987-03-01</date><risdate>1987</risdate><volume>59</volume><issue>5</issue><spage>703</spage><epage>708</epage><pages>703-708</pages><issn>0003-2700</issn><eissn>1520-6882</eissn><coden>ANCHAM</coden><abstract>Ammonium bis(2-hydroxyethyl)dithiocarbamate (HEDC) is used as a precolumn derivatizing reagent for the reversed-phase HPLC determination of Co(II), Cu(II), Hg(II), and Ni(II). The metal-HEDC complexes are soluble in water, which eliminates the need to extract them into an organic solvent prior to analysis. Co(II), Cu(II), and Ni(II) can be determined by direct aqueous injection onto a C18 column in the range of 0.005-10.0 mg/L, with a precision of 1.5-3.2%. Detection is at 405 nm. The Hg(II)-HEDC complex is preconcentrated on an on-line adsorption column prior to HPLC analysis. After preconcentration, Hg(II) can be determined in the range of 0.02-25..mu..g/L with a precision of less than 2%. The analysis of spiked electroplating waste waters showed good agreement with expected values.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/ac00132a005</doi><tpages>6</tpages></addata></record> |
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| ispartof | Anal. Chem.; (United States), 1987-03, Vol.59 (5), p.703-708 |
| issn | 0003-2700 1520-6882 |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_ac00132a005 |
| source | American Chemical Society Journals |
| subjects | 520200 -- Environment, Aquatic-- Chemicals Monitoring & Transport-- (-1989) AMMONIUM COMPLEXES Analytical chemistry CARBAMATES CARBONIC ACID DERIVATIVES CARBOXYLIC ACID SALTS CHEMICAL ANALYSIS CHEMICAL REACTIONS Chemistry Chromatographic methods and physical methods associated with chromatography CHROMATOGRAPHY COBALT COBALT COMPLEXES COMPLEXES COPPER COPPER COMPLEXES DATA DERIVATIZATION DITHIOLS ELEMENTS ENVIRONMENTAL SCIENCES Exact sciences and technology EXPERIMENTAL DATA HYDROGEN COMPOUNDS INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY LIQUID COLUMN CHROMATOGRAPHY LIQUID WASTES MERCURY MERCURY COMPLEXES METALS NICKEL NICKEL COMPLEXES NUMERICAL DATA ORGANIC COMPOUNDS ORGANIC NITROGEN COMPOUNDS ORGANIC SULFUR COMPOUNDS Other chromatographic methods OXYGEN COMPOUNDS QUANTITATIVE CHEMICAL ANALYSIS REAGENTS SEPARATION PROCESSES SOLUBILITY SOLVENT PROPERTIES THIOLS TRACE AMOUNTS TRANSITION ELEMENT COMPLEXES TRANSITION ELEMENTS WASTE WATER WASTES 400102 -- Chemical & Spectral Procedures WATER |
| title | Determination of cobalt, copper, mercury, and nickel as bis(2-hydroxyethyl)dithiocarbamate complexes by high-performance liquid chromatography |
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