Determination of sulfur compound distribution in petroleum by gas chromatography with a flame photometric detector
A simulated distillation using a flame photometric detector (FPD) is reported for determining the boiling range distribution of sulfur-containing compounds in middle-to-heavy petroleum distillates. Its success is based on a new calibration method for the FPD involving converting all the sulfur-conta...
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| Veröffentlicht in: | Anal. Chem.; (United States) 1986-12, Vol.58 (14), p.3017-3021 |
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| container_title | Anal. Chem.; (United States) |
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| creator | Bradley, Cherlynlavaughn Schiller, Douglas J |
| description | A simulated distillation using a flame photometric detector (FPD) is reported for determining the boiling range distribution of sulfur-containing compounds in middle-to-heavy petroleum distillates. Its success is based on a new calibration method for the FPD involving converting all the sulfur-containing compounds to SO/sub 2/ before detection and linearizing the data. A single calibration equation is formulated expressing a uniform and linear relationship between detector response and sulfur concentration for the various types of sulfur compounds in petroleum. Consequently, the problems of handling the detector's nonlinearity and variance of response to different sulfur compounds are eliminated. The method is quantitative and applicable to petroleum distillates with a final boiling point of 1184 /sup 0/F (640 /sup 0/C) and greater than or equal to850 ppm by weight total sulfur content. |
| doi_str_mv | 10.1021/ac00127a026 |
| format | Article |
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Its success is based on a new calibration method for the FPD involving converting all the sulfur-containing compounds to SO/sub 2/ before detection and linearizing the data. A single calibration equation is formulated expressing a uniform and linear relationship between detector response and sulfur concentration for the various types of sulfur compounds in petroleum. Consequently, the problems of handling the detector's nonlinearity and variance of response to different sulfur compounds are eliminated. The method is quantitative and applicable to petroleum distillates with a final boiling point of 1184 /sup 0/F (640 /sup 0/C) and greater than or equal to850 ppm by weight total sulfur content.</description><identifier>ISSN: 0003-2700</identifier><identifier>EISSN: 1520-6882</identifier><identifier>DOI: 10.1021/ac00127a026</identifier><identifier>CODEN: ANCHAM</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>02 PETROLEUM ; 023000 - Petroleum- Properties & Composition ; 400102 - Chemical & Spectral Procedures ; Applied sciences ; BOILING POINTS ; CALIBRATION STANDARDS ; CHALCOGENIDES ; CHEMICAL ANALYSIS ; CHROMATOGRAPHY ; Crude oil, natural gas and petroleum products ; DATA ; DISTILLATES ; DISTILLATION ; Energy ; ENERGY SOURCES ; Exact sciences and technology ; EXPERIMENTAL DATA ; FLAME PHOTOMETRY ; FOSSIL FUELS ; FUELS ; GAS CHROMATOGRAPHY ; INFORMATION ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; NUMERICAL DATA ; Other techniques and industries ; OXIDES ; OXYGEN COMPOUNDS ; PETROLEUM ; PETROLEUM DISTILLATES ; PETROLEUM FRACTIONS ; PHOTOMETRY ; PHYSICAL PROPERTIES ; Processing of crude oil and oils from shales and tar sands. Processes. Equipment. Refinery and treatment units ; QUANTITATIVE CHEMICAL ANALYSIS ; SEPARATION PROCESSES ; SULFUR COMPOUNDS ; SULFUR DIOXIDE ; SULFUR OXIDES ; THERMODYNAMIC PROPERTIES ; TRANSITION TEMPERATURE</subject><ispartof>Anal. 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Chem.; (United States)</title><addtitle>Anal. Chem</addtitle><description>A simulated distillation using a flame photometric detector (FPD) is reported for determining the boiling range distribution of sulfur-containing compounds in middle-to-heavy petroleum distillates. Its success is based on a new calibration method for the FPD involving converting all the sulfur-containing compounds to SO/sub 2/ before detection and linearizing the data. A single calibration equation is formulated expressing a uniform and linear relationship between detector response and sulfur concentration for the various types of sulfur compounds in petroleum. Consequently, the problems of handling the detector's nonlinearity and variance of response to different sulfur compounds are eliminated. The method is quantitative and applicable to petroleum distillates with a final boiling point of 1184 /sup 0/F (640 /sup 0/C) and greater than or equal to850 ppm by weight total sulfur content.</description><subject>02 PETROLEUM</subject><subject>023000 - Petroleum- Properties & Composition</subject><subject>400102 - Chemical & Spectral Procedures</subject><subject>Applied sciences</subject><subject>BOILING POINTS</subject><subject>CALIBRATION STANDARDS</subject><subject>CHALCOGENIDES</subject><subject>CHEMICAL ANALYSIS</subject><subject>CHROMATOGRAPHY</subject><subject>Crude oil, natural gas and petroleum products</subject><subject>DATA</subject><subject>DISTILLATES</subject><subject>DISTILLATION</subject><subject>Energy</subject><subject>ENERGY SOURCES</subject><subject>Exact sciences and technology</subject><subject>EXPERIMENTAL DATA</subject><subject>FLAME PHOTOMETRY</subject><subject>FOSSIL FUELS</subject><subject>FUELS</subject><subject>GAS CHROMATOGRAPHY</subject><subject>INFORMATION</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>NUMERICAL DATA</subject><subject>Other techniques and industries</subject><subject>OXIDES</subject><subject>OXYGEN COMPOUNDS</subject><subject>PETROLEUM</subject><subject>PETROLEUM DISTILLATES</subject><subject>PETROLEUM FRACTIONS</subject><subject>PHOTOMETRY</subject><subject>PHYSICAL PROPERTIES</subject><subject>Processing of crude oil and oils from shales and tar sands. Processes. Equipment. Refinery and treatment units</subject><subject>QUANTITATIVE CHEMICAL ANALYSIS</subject><subject>SEPARATION PROCESSES</subject><subject>SULFUR COMPOUNDS</subject><subject>SULFUR DIOXIDE</subject><subject>SULFUR OXIDES</subject><subject>THERMODYNAMIC PROPERTIES</subject><subject>TRANSITION TEMPERATURE</subject><issn>0003-2700</issn><issn>1520-6882</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1986</creationdate><recordtype>article</recordtype><recordid>eNqFkMFu1DAQhi0EEkvhxAtYVaUeUGBsx7H3WLbQIi2iUsvZchy7cZvEke0I9u1xSVVxqMRpDvP9M78-hN4T-EiAkk_aABAqNNDmBdoQTqFqpKQv0QYAWEUFwGv0JqW7ghEgzQbFc5ttHP2ksw8TDg6nZXBLxCaMc1imDnc-5ejb5e_eT3i2OYbBLiNuD_hWJ2z6GEadw23Uc3_Av3zuscZu0KPFcx9yGEvCG9yVTyaH-Ba9cnpI9t3jPEI_v3652V1W-x8X33Zn-0oz2eTKbRvGaCMcFbbdkloyDRJIbai03ArXUMmgsy3lhne1a1ta060TkvOOcyYsO0LH692QslfJ-PK-N2GaSgsloAYGdYE-rJCJIaVonZqjH3U8KALqwan6x2mhT1Z61snowUU9GZ-eIpIV2aX1_zC6rcvNglUrVgzb309rHe9VI5jg6ubqWu0vd993RHxWD11PV16bpO7CEqei79mefwD1RZ9v</recordid><startdate>19861201</startdate><enddate>19861201</enddate><creator>Bradley, Cherlynlavaughn</creator><creator>Schiller, Douglas J</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19861201</creationdate><title>Determination of sulfur compound distribution in petroleum by gas chromatography with a flame photometric detector</title><author>Bradley, Cherlynlavaughn ; Schiller, Douglas J</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a386t-f9633267f27eb91483a08014c28e5e7f62830deb25c5d4fbb2429f7855d5537e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1986</creationdate><topic>02 PETROLEUM</topic><topic>023000 - Petroleum- Properties & Composition</topic><topic>400102 - Chemical & Spectral Procedures</topic><topic>Applied sciences</topic><topic>BOILING POINTS</topic><topic>CALIBRATION STANDARDS</topic><topic>CHALCOGENIDES</topic><topic>CHEMICAL ANALYSIS</topic><topic>CHROMATOGRAPHY</topic><topic>Crude oil, natural gas and petroleum products</topic><topic>DATA</topic><topic>DISTILLATES</topic><topic>DISTILLATION</topic><topic>Energy</topic><topic>ENERGY SOURCES</topic><topic>Exact sciences and technology</topic><topic>EXPERIMENTAL DATA</topic><topic>FLAME PHOTOMETRY</topic><topic>FOSSIL FUELS</topic><topic>FUELS</topic><topic>GAS CHROMATOGRAPHY</topic><topic>INFORMATION</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>NUMERICAL DATA</topic><topic>Other techniques and industries</topic><topic>OXIDES</topic><topic>OXYGEN COMPOUNDS</topic><topic>PETROLEUM</topic><topic>PETROLEUM DISTILLATES</topic><topic>PETROLEUM FRACTIONS</topic><topic>PHOTOMETRY</topic><topic>PHYSICAL PROPERTIES</topic><topic>Processing of crude oil and oils from shales and tar sands. Processes. Equipment. Refinery and treatment units</topic><topic>QUANTITATIVE CHEMICAL ANALYSIS</topic><topic>SEPARATION PROCESSES</topic><topic>SULFUR COMPOUNDS</topic><topic>SULFUR DIOXIDE</topic><topic>SULFUR OXIDES</topic><topic>THERMODYNAMIC PROPERTIES</topic><topic>TRANSITION TEMPERATURE</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bradley, Cherlynlavaughn</creatorcontrib><creatorcontrib>Schiller, Douglas J</creatorcontrib><creatorcontrib>Amoco Corp., Naperville, IL</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Anal. Chem.; (United States)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bradley, Cherlynlavaughn</au><au>Schiller, Douglas J</au><aucorp>Amoco Corp., Naperville, IL</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Determination of sulfur compound distribution in petroleum by gas chromatography with a flame photometric detector</atitle><jtitle>Anal. Chem.; (United States)</jtitle><addtitle>Anal. Chem</addtitle><date>1986-12-01</date><risdate>1986</risdate><volume>58</volume><issue>14</issue><spage>3017</spage><epage>3021</epage><pages>3017-3021</pages><issn>0003-2700</issn><eissn>1520-6882</eissn><coden>ANCHAM</coden><abstract>A simulated distillation using a flame photometric detector (FPD) is reported for determining the boiling range distribution of sulfur-containing compounds in middle-to-heavy petroleum distillates. Its success is based on a new calibration method for the FPD involving converting all the sulfur-containing compounds to SO/sub 2/ before detection and linearizing the data. A single calibration equation is formulated expressing a uniform and linear relationship between detector response and sulfur concentration for the various types of sulfur compounds in petroleum. Consequently, the problems of handling the detector's nonlinearity and variance of response to different sulfur compounds are eliminated. The method is quantitative and applicable to petroleum distillates with a final boiling point of 1184 /sup 0/F (640 /sup 0/C) and greater than or equal to850 ppm by weight total sulfur content.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/ac00127a026</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0003-2700 |
| ispartof | Anal. Chem.; (United States), 1986-12, Vol.58 (14), p.3017-3021 |
| issn | 0003-2700 1520-6882 |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_ac00127a026 |
| source | ACS Publications |
| subjects | 02 PETROLEUM 023000 - Petroleum- Properties & Composition 400102 - Chemical & Spectral Procedures Applied sciences BOILING POINTS CALIBRATION STANDARDS CHALCOGENIDES CHEMICAL ANALYSIS CHROMATOGRAPHY Crude oil, natural gas and petroleum products DATA DISTILLATES DISTILLATION Energy ENERGY SOURCES Exact sciences and technology EXPERIMENTAL DATA FLAME PHOTOMETRY FOSSIL FUELS FUELS GAS CHROMATOGRAPHY INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY NUMERICAL DATA Other techniques and industries OXIDES OXYGEN COMPOUNDS PETROLEUM PETROLEUM DISTILLATES PETROLEUM FRACTIONS PHOTOMETRY PHYSICAL PROPERTIES Processing of crude oil and oils from shales and tar sands. Processes. Equipment. Refinery and treatment units QUANTITATIVE CHEMICAL ANALYSIS SEPARATION PROCESSES SULFUR COMPOUNDS SULFUR DIOXIDE SULFUR OXIDES THERMODYNAMIC PROPERTIES TRANSITION TEMPERATURE |
| title | Determination of sulfur compound distribution in petroleum by gas chromatography with a flame photometric detector |
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