Synthesis, characterization, and photocatalytic disinfection studies of porphyrin dimer/TiO2-based photocatalyst

In this research, we synthesized a novel panchromatic absorption dimer porphyrin and designed a dimer molecule with maximum absorption in the visible and NIR regions. The work was followed and monitored by its photocatalytic function with anatase TiO2 and brookite-rutile TiO2, and preliminarily comp...

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Veröffentlicht in:Journal of molecular structure 2021-07, Vol.1236, p.130276, Article 130276
Hauptverfasser: Kumar, Rangaraju Satish, Ryu, Jiwon, Kim, Hyorim, Mergu, Naveen, Park, Jae-Yeon, Shin, Hyun-Jin, Kim, Min Gu, Lee, Seung Geol, Son, Young-A
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Sprache:eng
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Zusammenfassung:In this research, we synthesized a novel panchromatic absorption dimer porphyrin and designed a dimer molecule with maximum absorption in the visible and NIR regions. The work was followed and monitored by its photocatalytic function with anatase TiO2 and brookite-rutile TiO2, and preliminarily compared and tested its photocatalytic disinfection of gram-negative bacteria Escherichia coli (E. coli) in visible light conditions toward the potential of future studies. The finding results were compared with the bare anatase TiO2 and brookite-rutile TiO2. The prepared structure of molecules was confirmed by SEM, EDS, XRD, XPS, and solid-state diffuse reflectance spectral studies.
ISSN:0022-2860
1872-8014
DOI:10.1016/j.molstruc.2021.130276