Percolation phenomena of dielectric permittivity of a microwave-sintered BaTiO3–Ag nanocomposite for high energy capacitor

In the present study, the Alkoxide-Hydroxide sol-gel process is utilized for the synthesis of barium titanate-silver (BaTiO3–Ag) nanocomposite in an inert atmosphere. The high value of dielectric constant having less tangent loss is obtained along with increasing conductivity with Ag content. Moreover, by the inclusion of the conductive phase in BaTiO3, the increasing value of dielectric properties with decreasing Curie temperature is investigated. Sintering of composites was done at 1100 °C for 20 min by using microwave sintering, to improve the densification of ceramic nanocomposites in lesser time with uniform grain size. By increasing the silver content, dielectric constant and tangent loss increased until the percolation threshold (∼5% Ag) achieved and suppression of formation of conducting path in composite occurred due to adhesion of silver on barium titanate. Also, at Tc in BaTiO3–Ag (3.5%), the highest value of dielectric constant (εr) (∼9 × 104 with tangent loss ∼0.06; several times larger than pure BaTiO3) was obtained due to well dispersion of silver particles in BaTiO3 matrix. •Alkoxide-Hydroxide sol-gel method is used for the synthesis of barium titanate-silver (BaTiO3–Ag) Nanocomposite in inert atmosphere.•In current investigation, a detailed study on enhancement of dielectric permittivity and the influences of microwave sintering condition on the properties of Ag–BaTiO3 composite is presented.•The effect of Ag nanoparticles on dielectric properties of BaTiO3 matrix is investigated by using different concentration of silver in composite.