Optical and thermal properties of l-tartaric doped KDP crystals

The impact of l-tartaric acid (LTA) doping on different properties of potassium dihydrogen phosphate single crystals grown by point seed rapid growth technique has been obtained. Powder X-ray diffraction (PXRD) analysis was completed to prove that the l-tartaric adding had no prominent effect on the...

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Veröffentlicht in:Optik (Stuttgart) 2020-02, Vol.203, p.163967, Article 163967
Hauptverfasser: Mao, Caiju, Zhou, Guanggang, Sun, Xiaoliang, Li, Gang, Wang, Jingying, Wu, Haicheng, Sun, Wei, Lu, Guiwu
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Sprache:eng
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Zusammenfassung:The impact of l-tartaric acid (LTA) doping on different properties of potassium dihydrogen phosphate single crystals grown by point seed rapid growth technique has been obtained. Powder X-ray diffraction (PXRD) analysis was completed to prove that the l-tartaric adding had no prominent effect on the unit cell parameters. The existence of various functional groups were identified by FT-IR spectroscopy. Optical transmittance of the grown crystal has been studied by UV–Vis-NIR spectral analysis, indicating that the transmittance of crystals increased with the addition of l-tartaric, and the optical transmittance reached an optimum value at 1mol% doping concentration. Thermal stability measurement was carried out by TG-DTA study. This paper also analyzed the band gap and refractive index of l-tartaric acid doped KDP, and the physicochemical mechanism of adding on the effect of optical properties of KDP crystal was also discussed.
ISSN:0030-4026
1618-1336
DOI:10.1016/j.ijleo.2019.163967