Elucidating the distribution and sources of street dust bound PAHs in Durgapur, India: A probabilistic health risk assessment study by Monte-Carlo simulation

Spatial and seasonal distribution of PAHs, source identification, and their associated carcinogenic health risk was investigated in street dust of Durgapur, India. Street dust is an important indicator to detect the quality of the environment as well as the sources of pollutants. The obtained results showed fluctuation in PAHs concentrations from 2317 ± 402 ng/g to 5491 ± 2379 ng/g along with the sampling sites. Seasonal variation revealed higher PAHs concentrations in the winter season (5401 ± 993 ng/g) with the maximum presence of 4-ring PAHs. Two-way analysis of variance (ANOVA) exposed that the sites, seasons and site-season interactions were vividly affected by dissimilar PAHs. The PAHs source identification was investigated by principal component analysis (PCA), positive matrix factorization (PMF), diagnostic ratios, and they revealed pyrogenic, diesel, gasoline, wood and coal combustion to be the key sources of the PAHs in street dust. Obtained results from incremental lifetime cancer risk (ILCR) model exhibited the carcinogenic risk for children ranged from 2.4E-06 to 3.8E-06 while 2.1E-06 to 3.4E-06 for adults which were above the baseline value 1.0E-06. The Monte Carlo simulation model identified cumulative cancer risk of sixteen PAHs in 50th percentile were 2.8 and 1.7 times more while in 95th percentile, the values were 8.8 and 7.8 times higher than the acceptable value of 1E-06 for child and adult respectively. [Display omitted] •Street dust PAHs was higher in winter; especially dominated by 4-ring PAHs.•Pyrogenic, vehicular and coal/wood combustion are the PAH sources in street dust.•ILCR model revealed potential cancer risk for children and adults in near future.•Monte-Carlo simulation (95th percentile) shows 7–9 times high risk than the limit of 10−6. PAHs concentration was higher in the winter season and highway areas with pyrogenic, traffic, coal, and wood combustion sources. Monte-Carlo simulation identified cumulative cancer risk of PAHs (50th percentile) > 1.7 and 2.8 times of 1E-06 for adult and child, respectively.