Preparation of micron-sized nonspherical polystyrene/poly(styrene-co-ethyleneglycol dimethacrylate) particles by seeded soap-free emulsion polymerization

Micron-sized nonspherical polymer particles having different morphologies were synthesized by seeded soap-free emulsion polymerization of styrene (St) and ethyleneglycol dimethacrylate (EGDMA, used as a crosslinker) on spherical, linear polystyrene (PS) seed particles. The morphology of the resultin...

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Veröffentlicht in:Chinese journal of polymer science 2011-09, Vol.29 (5), p.634-638
Hauptverfasser: Wang, Ze-feng, Wang, Tao, Bian, Li-na, Zhou, Li-min, Shi, Shan, Kuroda, Shin-ichi
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Sprache:eng
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Zusammenfassung:Micron-sized nonspherical polymer particles having different morphologies were synthesized by seeded soap-free emulsion polymerization of styrene (St) and ethyleneglycol dimethacrylate (EGDMA, used as a crosslinker) on spherical, linear polystyrene (PS) seed particles. The morphology of the resulting PS/poly(St- co -EGDMA) particles was dependent on the crosslinker concentration and polymerization temperature.
ISSN:0256-7679
1439-6203
DOI:10.1007/s10118-011-1062-6