Design of a zeolite capsule catalyst by controlling the support size for the direct synthesis of isoparaffin
Three kinds of H-ZSM-5 zeolite capsule catalysts were prepared on Co/SiO 2 catalyst pellets of different sizes. Characterization of the catalysts indicated that a defect-free H-ZSM-5 membrane had been constructed successfully on the Co/SiO 2 surface. The smaller Co/SiO 2 pellets were favorable for z...
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| Veröffentlicht in: | Research on chemical intermediates 2008-01, Vol.34 (8-9), p.771-779 |
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| container_title | Research on chemical intermediates |
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| creator | Yang, Guohui He, Jingjiang Yoneyama, Yoshiharu Tan, Yisheng Han, Yizhuo Tsubaki, Noritatsu |
| description | Three kinds of H-ZSM-5 zeolite capsule catalysts were prepared on Co/SiO
2
catalyst pellets of different sizes. Characterization of the catalysts indicated that a defect-free H-ZSM-5 membrane had been constructed successfully on the Co/SiO
2
surface. The smaller Co/SiO
2
pellets were favorable for zeolite capsule growth under the same synthesis conditions. Zeolite capsule catalysts, especially the catalysts with smaller pellet sizes, had a higher isoparaffin selectivity compared with conventional FTS Co/SiO
2
catalyst and mixed catalyst of Co/SiO
2
with H-ZSM-5 zeolite. |
| doi_str_mv | 10.1007/BF03036937 |
| format | Article |
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2
catalyst pellets of different sizes. Characterization of the catalysts indicated that a defect-free H-ZSM-5 membrane had been constructed successfully on the Co/SiO
2
surface. The smaller Co/SiO
2
pellets were favorable for zeolite capsule growth under the same synthesis conditions. Zeolite capsule catalysts, especially the catalysts with smaller pellet sizes, had a higher isoparaffin selectivity compared with conventional FTS Co/SiO
2
catalyst and mixed catalyst of Co/SiO
2
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2
catalyst pellets of different sizes. Characterization of the catalysts indicated that a defect-free H-ZSM-5 membrane had been constructed successfully on the Co/SiO
2
surface. The smaller Co/SiO
2
pellets were favorable for zeolite capsule growth under the same synthesis conditions. Zeolite capsule catalysts, especially the catalysts with smaller pellet sizes, had a higher isoparaffin selectivity compared with conventional FTS Co/SiO
2
catalyst and mixed catalyst of Co/SiO
2
with H-ZSM-5 zeolite.</description><subject>Catalysis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Inorganic Chemistry</subject><subject>Physical Chemistry</subject><issn>0922-6168</issn><issn>1568-5675</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNptkLFOwzAURS0EEqWw8AWeQYHnhNjxCIUCUiUWmCPbsYurYEd-7pB-PSlFYmG6ekdHV0-XkEsGNwxA3D4soYKKy0ockRmreVPUXNTHZAayLAvOeHNKzhA3AKxuGpiR_tGiXwcaHVV0Z2Pvs6VGDbjt95lVP2KmeqQmhpxi3_uwpvnTUtwOQ0yZot9Z6mL6gZ1P1kxsDNOFHve1HuOgknLOh3Ny4lSP9uI35-Rj-fS-eClWb8-vi_tVYZgUuSi14tJofuckV7wRymrjyhKg0tIyowyoDrQsO8cmrIVgnauYkZbXnVHaVXNydeg1KSIm69oh-S-VxpZBu9-p_dtpkq8PMk5SWNvUbuI2hem__-xvn4Frhw</recordid><startdate>20080101</startdate><enddate>20080101</enddate><creator>Yang, Guohui</creator><creator>He, Jingjiang</creator><creator>Yoneyama, Yoshiharu</creator><creator>Tan, Yisheng</creator><creator>Han, Yizhuo</creator><creator>Tsubaki, Noritatsu</creator><general>Springer Netherlands</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20080101</creationdate><title>Design of a zeolite capsule catalyst by controlling the support size for the direct synthesis of isoparaffin</title><author>Yang, Guohui ; He, Jingjiang ; Yoneyama, Yoshiharu ; Tan, Yisheng ; Han, Yizhuo ; Tsubaki, Noritatsu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c197t-2ba69cb64f96a687aebcf22003b9e1cac0ad0b92df1f22b771df31c9e65dcabf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Catalysis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Inorganic Chemistry</topic><topic>Physical Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yang, Guohui</creatorcontrib><creatorcontrib>He, Jingjiang</creatorcontrib><creatorcontrib>Yoneyama, Yoshiharu</creatorcontrib><creatorcontrib>Tan, Yisheng</creatorcontrib><creatorcontrib>Han, Yizhuo</creatorcontrib><creatorcontrib>Tsubaki, Noritatsu</creatorcontrib><collection>CrossRef</collection><jtitle>Research on chemical intermediates</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yang, Guohui</au><au>He, Jingjiang</au><au>Yoneyama, Yoshiharu</au><au>Tan, Yisheng</au><au>Han, Yizhuo</au><au>Tsubaki, Noritatsu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Design of a zeolite capsule catalyst by controlling the support size for the direct synthesis of isoparaffin</atitle><jtitle>Research on chemical intermediates</jtitle><stitle>Res. Chem. Intermed</stitle><date>2008-01-01</date><risdate>2008</risdate><volume>34</volume><issue>8-9</issue><spage>771</spage><epage>779</epage><pages>771-779</pages><issn>0922-6168</issn><eissn>1568-5675</eissn><abstract>Three kinds of H-ZSM-5 zeolite capsule catalysts were prepared on Co/SiO
2
catalyst pellets of different sizes. Characterization of the catalysts indicated that a defect-free H-ZSM-5 membrane had been constructed successfully on the Co/SiO
2
surface. The smaller Co/SiO
2
pellets were favorable for zeolite capsule growth under the same synthesis conditions. Zeolite capsule catalysts, especially the catalysts with smaller pellet sizes, had a higher isoparaffin selectivity compared with conventional FTS Co/SiO
2
catalyst and mixed catalyst of Co/SiO
2
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| ispartof | Research on chemical intermediates, 2008-01, Vol.34 (8-9), p.771-779 |
| issn | 0922-6168 1568-5675 |
| language | eng |
| recordid | cdi_crossref_primary_10_1007_BF03036937 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Catalysis Chemistry Chemistry and Materials Science Inorganic Chemistry Physical Chemistry |
| title | Design of a zeolite capsule catalyst by controlling the support size for the direct synthesis of isoparaffin |
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