Preparation and etherification reaction of fatty dichlorocyclopropanes

Preparation and etherification reaction of fatty dichlorocyclopropanes

Dichlorocarbene was added tocis‐9‐octadecene, methyl oleate, methyl elaidate, and methyl linoleate to form the corresponding mono‐ or bis‐dichlorocyclopropanes in yields of 75舑88%. The dichlorocyclopropanes underwent ring‐opening substitution on heating with alcohols (or water) to form ॆ‐chlorallyli...

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Veröffentlicht in:Journal of the American Oil Chemists' Society 1964-01, Vol.41 (1), p.82-85
Hauptverfasser: Kenney, H. E., Komanowsky, Daria, Cook, Linda L., Wrigley, A. N.
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container_issue 1
container_start_page 82
container_title Journal of the American Oil Chemists' Society
container_volume 41
creator Kenney, H. E.
Komanowsky, Daria
Cook, Linda L.
Wrigley, A. N.
description Dichlorocarbene was added tocis‐9‐octadecene, methyl oleate, methyl elaidate, and methyl linoleate to form the corresponding mono‐ or bis‐dichlorocyclopropanes in yields of 75舑88%. The dichlorocyclopropanes underwent ring‐opening substitution on heating with alcohols (or water) to form ॆ‐chlorallylic ethers (or alcohols). The ethers were obtained in yields of 46 to 84%. Tetraethylene glycol and methyl lactate, as hydroxyl compounds, gave a polyethenoxy ester and an ether‐linked diester, respectively.
doi_str_mv 10.1007/BF02661913
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title Preparation and etherification reaction of fatty dichlorocyclopropanes
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