Isotopic effects during catalytic hydrogenation

No isotopic discrimination is observed during catalytic reduction of methyl oleate with hydrogen‐tritium gas mixtures. One explanation may be that at atmospheric pressure and 40C the isotopic effect on solubility is small and the concentration of the dissolved hydrogen isotopes is rate limiting. Tri...

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Veröffentlicht in:	J. Am. Oil Chemists' Soc 1964-01, Vol.41 (1), p.1-3
Hauptverfasser:	Bitner, E. D., Selke, E., Rohwedder, W. K., Dutton, H. J.
Format:	Artikel
Sprache:	eng
Schlagworte:	ALKENES CATALYSIS CHEMICAL REACTIONS CHEMISTRY CONFIGURATION DEUTERIUM GASES HYDROGEN HYDROGENATION IONIZATION CHAMBERS ISOTOPE EFFECTS LABELLED COMPOUNDS LABORATORY EQUIPMENT MASS SPECTROMETERS MEASURED VALUES METHYL RADICALS MIXING MOLECULES OLEIC ACID OPERATION ORGANIC ACIDS PLANNING PREPARATION PRESSURE QUALITATIVE ANALYSIS QUANTITY RATIO REACTION KINETICS RECORDING SYSTEMS REDUCTION SOLUBILITY TRACER TECHNIQUES TRITIUM
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